flavosemiquinone
National Institutes of Health
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Photoinduced biochemical reactions are ubiquitously governed by derivatives of flavin, which is a key player in a manifold of…
Light-induced radicals were detected by electron paramagnetic resonance (EPR) and pulsed electron-nuclear double resonance (ENDOR…
We have shown that envelope membranes from spinach chloroplasts contain (i) semiquinone and flavosemiquinone radicals, (ii) a…
Glycolate oxidase from spinach has been expressed in Saccharomyces cerevisiae. The active enzyme was purified to near-homogeneity…
The trimethylamine dehydrogenase of bacterium W3A1 is reduced with the formation of a triplet state in which two electrons…
The neutral flavosemiquinone has been studied in detail by electron spectroscopy. Isotopic (15N, 2H) and chemical substitutions…
The dependence on pH of the disproportionation of the flavosemiquinone has been investigated by ESR. For 3-alkylated lumiflavin…