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cyclopropenone

National Institutes of Health

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Cyclopropanes

Papers overview

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2016
2016
Cyclopropenone-caged Sondheimer diyne (dibenzo[a,e]cyclooctadiyne): a photoactivatable linchpin for efficient SPAAC crosslinking.
The first fully conjugated bis-cyclopropenone (photo-DIBOD), a derivative of dibenzo[a,e][8]annulene, has been synthesized. 350… 
2014
2014
INVESTIGATING THE MINIMUM ENERGY PRINCIPLE IN SEARCHES FOR NEW MOLECULAR SPECIES—THE CASE OF H2C3O ISOMERS
Recently, Lattelais et al. have interpreted aggregated observations of molecular isomers to suggest that there exists a “minimum… 
2014
2014
Photodecarbonylation mechanism of cyclopropenone in the gas phase: electronic structure calculation and AIMS dynamics simulation.
In this article, structures and energies of cyclopropenone in the low-lying electronic states have been determined by the CASSCF… 
2010
2010
Design of living ring-opening alkyne metathesis.
Despite the tremendous impact of alkene ring-opening metathesis polymerization (ROMP) on the design and the synthesis of polymers… 
2010
2010
Poly(cyclopropenone)s: formal inclusion of the smallest Hückel aromatic into pi-conjugated polymers.
The synthesis of precursors to pi-conjugated cyclopropenium polymers is described. Monomers for chemical and electrochemical… 
2005
2005
Application of photochemical decarbonylation of cyclopropenones for the in situ generation of reactive enediynes. Construction of a cyclopropenone-containing enediyne precursor by using a…
[reaction: see text] A cyclopropenone-containing enediyne photoprecursor, 6-tert-butyldimethylsilyloxy-3-(alpha-hydroxybenzyl… 
2000
2000
Asymmetric construction of quaternary carbon centers by regio- and enantiocontrolled allylzincation
An allylic zinc reagent bearing a chiral bisoxazoline ligand adds to a substituted cyclopropenone acetal to produce an optically… 
1997
1997
Electronic Structure and Unimolecular Reactions of Cyclopropenone Carbonyl Oxide. A Theoretical Study.
A theoretical investigation on the lowest singlet and triplet potential energy surfaces of cyclopropenone carbonyl oxide 1 is… 
1996
1996
Selectivities in carbometalation of olefins. Experimental and theoretical studies
Abstract 
1994
1994
Synthetic Chemistry of Cyclopropenone Acetals
A variety of substituted cyclopropenone acetals have been prepared and studied for the purpose of gaining further insights into… 
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