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cyclopropenone

National Institutes of Health

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Cyclopropanes

Papers overview

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2020
2020
Selective [3 + 2] Cycloaddition of Cyclopropenone Derivatives and Elemental Chalcogens.
A highly efficient method is disclosed for the synthesis of 1,2-dichalcogen heterocycles via [3 + 2] cycloaddition of… 
Highly Cited
2019
Highly Cited
2019
Inverse Electron Demand Diels-Alder Reactions of Heterocyclic Azadienes, 1-Aza-1,3-Butadienes, Cyclopropenone Ketals, and Related Systems. A Retrospective.
A summary of the investigation and applications of the inverse electron demand Diels-Alder reaction is provided that have been… 
2016
2016
Cyclopropenone-caged Sondheimer diyne (dibenzo[a,e]cyclooctadiyne): a photoactivatable linchpin for efficient SPAAC crosslinking.
The first fully conjugated bis-cyclopropenone (photo-DIBOD), a derivative of dibenzo[a,e][8]annulene, has been synthesized. 350… 
Highly Cited
2015
Highly Cited
2015
A Bioorthogonal Ligation of Cyclopropenones Mediated by Triarylphosphines.
Bioorthogonal chemistries have been widely used to probe biopolymers in living systems. To date, though, only a handful of… 
2014
2014
INVESTIGATING THE MINIMUM ENERGY PRINCIPLE IN SEARCHES FOR NEW MOLECULAR SPECIES—THE CASE OF H2C3O ISOMERS
Recently, Lattelais et al. have interpreted aggregated observations of molecular isomers to suggest that there exists a “minimum… 
2010
2010
Intramolecular Diels-Alder reactions of cyclopropenone ketals.
The first intramolecular cycloaddition reactions of cyclopropenone ketals with tethered electron-deficient, electron-rich, and… 
2008
2008
Pathways to Oxygen-Bearing Molecules in the Interstellar Medium and in Planetary Atmospheres: Cyclopropenone (c-C3H2O) and Propynal (HCCCHO)
We investigated the formation of two C3H2O isomers, i.e., cyclopropenone (c-C3H2O) and propynal (HCCCHO), in binary ice mixtures… 
2005
2005
Application of photochemical decarbonylation of cyclopropenones for the in situ generation of reactive enediynes. Construction of a cyclopropenone-containing enediyne precursor by using a…
[reaction: see text] A cyclopropenone-containing enediyne photoprecursor, 6-tert-butyldimethylsilyloxy-3-(alpha-hydroxybenzyl… 
2005
2005
Photoswitchable enediynes: use of cyclopropenone as photocleavable masking group for the enediyne triple bond.
Cyclopropenone , 2,3-benzobicyclo[8.1.0]undec-1(10)-en-4-yn-11-one, is a thermally stable compound showing no signs of… 
2001
2001
Searches for new interstellar molecules, including a tentative detection of aziridine and a possible detection of propenal.
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