crotylsilane
National Institutes of Health
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The diastereoselectivity of the addition of (E)-2-butenyltrimethylsilane to acetaldehyde under electrophilic (BF3, H3O(+)) and…
Enantiomerically pure α-substituted crotylsilane reagents I and ent-I undergo asymmetric aldehyde crotylation followed by Ir(I…
Synthesis and preliminary biological evaluation of a 35-member library of bistramide A stereoisomers are reported. All eight…
[structure: see text] The first enantioselective synthesis of the polyketide antibiotics basiliskamides A and B, which exhibit…