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- Publications
- Influence
Catalytic asymmetric synthesis.
- S. Denmark, E. Jacobsen
- Chemistry, Medicine
- Accounts of chemical research
- 24 May 2000
On the mechanism of the Skraup-Doebner-Von Miller quinoline synthesis.
- S. Denmark, S. Venkatraman
- Chemistry, Medicine
- The Journal of organic chemistry
- 24 January 2006
The mechanism of the formation of substituted quinolines from anilines and alpha,beta-unsaturated ketones has been studied by the use of 13C-labeled ketones in cross-over experiments. In the reaction… Expand
Lewis base catalysis in organic synthesis.
- S. Denmark, G. Beutner
- Chemistry, Medicine
- Angewandte Chemie
- 15 February 2008
The legacy of Gilbert Newton Lewis (1875-1946) pervades the lexicon of chemical bonding and reactivity. The power of his concept of donor-acceptor bonding is evident in the eponymous foundations of… Expand
Total synthesis of RK-397.
- S. Denmark, S. Fujimori
- Chemistry, Medicine
- Journal of the American Chemical Society
- 7 June 2005
An enantioselective synthesis of the polyene macrolide RK-397 is described. The use of the same eight-carbon building block twice for the construction of the polyol chain allowed for a highly… Expand
A comparison of (chloromethyl)- and (iodomethyl)zinc cyclopropanation reagents
- S. Denmark, J. P. Edwards
- Chemistry
- 1 December 1991
Intramolecular silicon-assisted cross-coupling: total synthesis of (+)-brasilenyne.
- S. Denmark, S. Yang
- Chemistry, Medicine
- Journal of the American Chemical Society
- 27 November 2002
The first, total synthesis of (+)-brasilenyne (1) has been achieved in 19 steps from l-(S)-malic acid. The key elements of this approach are a highly diastereoselective ring-opening of a… Expand
Topics in Stereochemistry: Denmark/Topics in Stereochemistry, V25
- S. Denmark, J. Siegel
- Chemistry
- 12 April 2006
Solution- and solid-state structural studies of (halomethyl)zinc reagents
- S. Denmark, J. P. Edwards, S. Wilson
- Chemistry
- 1 March 1992
(Halomethyl)zinc cyclopropanation reagents have been investigated by solution NMR and X-ray crystallographic methods. Treatment of glycol-ether complexes of diethylzinc with chloroiodomethane or… Expand
Organocerium Additions to Chiral α,α-Dialkoxy Hydrazones: Asymmetric Synthesis of N-Protected α-Amino Acetals and α-Amino Aldehydes
- S. Denmark, Olivier J.-C. Nicaise
- Chemistry
- 1 May 1993
A general and selective procedure for the diastereoselective additions of organocerium reagents to chiral α,α-dialkoxy hydrazones has been developed. The best reagent combination involved a 6:1… Expand