corrolazine
National Institutes of Health
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Electronic structure calculations have been performed on four different Mn corrole and corrolazine complexes to clarify the role…
N-bridged dimers of tetrapyrroles complexed by transition metals have been known for nearly four decades, and gained renewed…
This work demonstrates that the Fe(H2O2) complex, which has been considered as an unlikely oxidant in P450, is actually very…
Manganese(V)-oxo corrole and corrolazine have been studied with ab initio multiconfiguration reference methods (CASPT2 and RASPT2…
The activation of dioxygen and its analogues, such as hydrogen peroxide, by metalloporphyrins leads to the generation of high…
As part of our efforts to develop the transition metal chemistry of corrolazines, which are ring-contracted porphyrinoid species…
To contribute to the fundamental picture of the electronic structure of high valent first row transition metal complexes, I have…
The syntheses of the first transition metal corrolazine complexes, in which the meso carbon atoms of a corrole framework have…