carbene, 13C-labeled
National Institutes of Health
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A library of 14 heterobis(carbene) complexes of the general formula [Au(iPr2-bimy)(ADC)]BF4 (7-20) containing the N-heterocyclic…
endo-2-Trimethylsilyl-anti-7-norbornyl triflate undergoes solvolysis reactions 1.8 × 10(4) faster than 7-norbornyl triflate in…
The title compound, C27H38N2, is the first reported free imidazolidin-2-ylidene carbene with 2,6-diisopropylphenyl groups in the…
Three C−X bond formation mechanisms observed in the oxidation of (HBpz3)ReO(R)(OTf) [HBpz3 = hydrotris(1-pyrazolyl)borate; R = Me…
Cross-coupling carbenes: The coupling of a propargylic ester with a diazoalkane in the presence of [RuCl(cod)Cp*] catalyst leads…
Oxidative insertion of the In(I) 'carbene analogues', [In{N(Dipp)C(Me))2CH] (Ar = Dipp = 2,6-iPr2C6H3; Ar = Mes = 2,4,6-Me3C6H2…
Reactions of dibromocyclopropane 2a, containing two spiro-fused 1,3-dioxane rings, with MeLi gave only the methylation products 8…
Reactions of dibromocyclopropane 2a, containing two spiro-fused 1,3-dioxane rings, with MeLi gave only the methylation products 8…
Although &valent carbon ccmpounds (carbenes) R’-E-R are an unportant class o f short-hved and reactive intermediates, there IS…