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carbanion

National Institutes of Health

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Broader (1)

Anions
Carbon ion

Papers overview

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Highly Cited
2009
Highly Cited
2009
Formal highly enantioselective organocatalytic addition of fluoromethyl anion to alpha,beta-unsaturated aldehydes.
Symmetric fluoromethylation made easy: a highly enantioselective fluoromethyl addition to ?,?-unsaturated aldehydes is described… 
Highly Cited
2005
Highly Cited
2005
Carbanion-mediated photocages: rapid and efficient photorelease with aqueous compatibility.
A new photocage is proposed, based on ketoprofen-derived compounds and mediated by carbanions. The new photocage has significant… 
2004
2004
Ligand-induced conformational changes and a reaction intermediate in branched-chain 2-oxo acid dehydrogenase (E1) from Thermus thermophilus HB8, as revealed by X-ray crystallography.
Highly Cited
2001
Highly Cited
2001
C--N bond formation on addition of aryl carbanions to the electrophilic nitrido ligand in TpOs(N)Cl(2).
The osmium(VI) nitrido complex TpOs(N)Cl(2) (1) has been prepared from K[Os(N)O(3)] and KTp in aqueous ethanolic HCl. It reacts… 
Highly Cited
1997
Highly Cited
1997
Asymmetric [2,3]-Wittig rearrangement as a general tool for asymmetric synthesis
Abstract 
Review
1991
Review
1991
Oxygenase side reactions of acetolactate synthase and other carbanion-forming enzymes.
Enzymes that mediate carbanion chemistry must protect their reactants from solvent and undesirable electrophiles, such as… 
Highly Cited
1987
Highly Cited
1987
Biosynthetic thiolase from zoogloea ramigera. I. Preliminary characterization and analysis of proton transfer reaction.
Review
1981
Review
1981
Methylation techniques in the structural analysis of glycoproteins and glycolipids.
1980
1980
Enzyme-activated inhibitors, alternate substrates, and a dead end inhibitor of the general acyl-CoA dehydrogenase.
1973
1973
Studies on the elimination reaction of D-amino acid oxidase with -amino- -chlorobutyrate. Further evidence for abstraction of substrate -hydrogen as a proton.
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