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bispidine

National Institutes of Health

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Bridged Bicyclo Compounds, Heterocyclic

Papers overview

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2020
2020
Spin state and reactivity of iron(iv)oxido complexes with tetradentate bispidine ligands.
The iron(iv)oxido complex [(bispidine)FeIV[double bond, length as m-dash]O(Cl)]+ is shown by experiment and high-level DLPNO-CCSD… 
2017
2017
Modulation of prion polymerization and toxicity by rationally designed peptidomimetics.
Misfolding and aggregation of cellular prion protein is associated with a large array of neurological disorders commonly called… 
2013
2013
Benzyl bispidine as an efficient replacement for (−)-sparteine in ring opening polymerisation
The synthesis and application of a dibenzyl-functionalized bispidine, in combination with 1-(3,5-bis(trifluoromethyl)phenyl)-3… 
2012
2012
Dioxygen reactivity of new bispidine-copper complexes.
The reactivity of copper complexes of three different second-generation bispidine-based ligands (bispidine = 3,7-diazabicyclo[3.3… 
2011
2011
Modular synthesis of functionalized bis-bispidine tetraazamacrocycles.
An effective synthesis is reported for the construction of highly rigid and preorganized bis-bispidine tetraazamacrocycles… 
2009
2009
Novel bispidine ligands and their first-row transition metal complexes: trigonal bipyramidal and trigonal prismatic geometries.
Four very rigid second generation bispidine-based ligands (bispidine = 3,7-diazabicyclo[3.3.1]nonane; tetra-, penta- and… 
2009
2009
Mechanisms of C – H bond activation : rich synergy between computation and experiment
Highly Cited
2008
Highly Cited
2008
Trinuclear {M1}CN{M2}2 complexes (M1 = Cr(III), Fe(III), Co(III); M2 = Cu(II), Ni(II), Mn(II)). Are single molecule magnets predictable?
The reaction of the hexacyanometalates K3[M(1)(CN)6] (M(1) = Cr(III), Fe(III), Co(III)) with the bispidine complexes [M(2)(L(1… 
2007
2007
Electronic structure of bispidine iron(IV) oxo complexes.
The electronic structure, based on DFT calculations, of a range of FeIV=O complexes with two tetra- (L1 and L2) and two isomeric… 
2002
2002
Utility of calculated 13C NMR chemical shifts in differentiating conformational isomers: a study of metal-complexed and uncomplexed bispidines.
Calculated 13C NMR chemical shifts were key to assigning the structures of the conformational forms of complexed and uncomplexed… 
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