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bis(dithiolene)tungsten

National Institutes of Health

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2 relations

Narrower (1)

DT-W(IV)

Broader (1)

Organometallic Compounds

Papers overview

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2012
2012
O-atom exchange between H2O and CO2 mediated by a bis(dithiolene)tungsten complex.
Inspired by the CO(2)-reductatse activity of tungsten-dependent formate dehydrogenases (W-FDHs), a reduced W-FDH model, [W(IV)(OH… 
2007
2007
Synthesis and structures of bis(dithiolene)tungsten(IV,VI) thiolate and selenolate complexes: approaches to the active sites of molybdenum and tungsten formate dehydrogenases.
Formate dehydrogenases are molybdenum- or tungsten-containing enzymes that catalyze the oxidation of formate to carbon dioxide… 
2005
2005
Reaction systems related to dissimilatory nitrate reductase: nitrate reduction mediated by bis(dithiolene)tungsten complexes.
Kinetics of the oxygen atom transfer reactions [M(IV)(QC6H2-2,4,6-Pr(i)3)(S2C2Me2)2]1- + XO --> [M(VI)O(QC6H2-2,4,6-Pr(i)3… 
2004
2004
An expanded set of functional groups in bis(dithiolene)tungsten(IV,VI) complexes related to the active sites of tungstoenzymes, Including WIV-SR and WVI-O(SR).
The active sites of tungstoenzymes have the formulations W(IV,V)L(S(2)pd)(2) and W(VI)LL'(S(2)pd)(2), in which two… 
2001
2001
Substitution and oxidation reactions of bis(dithiolene)tungsten complexes of potential relevance to enzyme sites.
Structurally characterized tungstoenzymes contain mononuclear active sites in which tungsten is coordinated by two pterin… 
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