Jian-Bing Jiang

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Three anion-cation compounds 1-3 with formula [M(phen)(3)][Cd(4)(SPh)(10)]·Sol (M = Ru(2+), Fe(2+), and Ni(2+), Sol = MeCN and H(2)O) have been synthesized and characterized by single-crystal analysis. Both the cations and anion are well-known ions, but the properties of the co-assembled compounds are interesting. Molecular structures and charge-transfer(More)
Most metal-1,10-phenanthroline-complex-sensitized inorganic semiconductors are multicomponent materials. This fundamental study was devoted to the single-phase materials fused with moieties of the phen complex and inorganic chalcogenide. Compounds 1 and 2 are new types of cubic clusters with cluster-to-ligand charge transfer.
A series of supertetrahedral polymers of chalcogenometalates (T3 cluster compounds) integrated with M-phen complexes (phen =1,10-phenanthroline; M = Ni, Fe) was prepared by a similar solvothermal technique. Compound [Fe(phen)(3)](4)[H(4)In(20)S(38)]·Hphen·3HDMA·8H(2)O (Mp-InS-4) (DMA = dimethylamine) is a 1-D straight chain. Compounds(More)
The preparation and crystal structure of a large wheel-shaped indium-telluride compound are reported. The inorganic cluster is decorated with 1,2-diaminocyclohexane molecules that play an important role in the formation of the nanoring. A related new 1D polymeric InTe compound is also presented in order to understand the effect of acidity on the formation(More)
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