aminocarbene
National Institutes of Health
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A new series of Fischer carbenes have been synthetized and examined as hole-transporting or electron-transporting layers (HTLs or…
Reaction of [Mo2 Cp2 (μ-κ1 :κ1 ,η6 -PMes*)(CO)2 ] with S or Se followed by protonation with [H(OEt2 )2 ](BAr'4 ) gave the…
The present work is aimed at designing novel organometallic push-pull species. To this end, different transition metal complexes…
A density functional theory (DFT) calculated conformation analysis of the twelve possible conformations of [Mo(CO)4(PPh3){C(NHCy…
The sequential addition of H⁺ and H⁻ ions to [Mo₂Cp₂(μ-κ²P,S:κ¹P,η⁴-SPMes*)(CNtBu)(CO)₂] (Mes* = 2,4,6-C₆H₂tBu₃) completes a…
Deprotonated Fischer-type aminocarbene complexes, (CO)5M=C(NR2)CH3 (M = Cr or W; R = Me or propyl), react with Ph3PAu+ by metal…
1,2-Dyotropic rearrangement can be induced by irradiation of properly functionalized Fischer carbenes. This novel reaction takes…
B3LYP/6-31G* calculations were carried out on adducts formed by the interaction of a cyclic unsaturated aminocarbene with…
The introduction of heavy atoms into protein crystals is sometimes rendered difficult and tedious because of the poor specificity…
The use of alkynylaminocarbene complexes of chromium as starting material for the synthesis of pyrroloindole, pyrrolochinoline…