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alstonisine

National Institutes of Health

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Indoles

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2018
2018
Enantioselective Synthesis of the Spirotropanyl Oxindole Scaffold through Bimetallic Relay Catalysis.
Spirotropanyl oxindole alkaloids like alstonisine and chitosenine show a wide range of bioactivites. We report the first… 
2017
2017
Concise Total Synthesis of (-)-Affinisine Oxindole, (+)-Isoalstonisine, (+)-Alstofoline, (-)-Macrogentine, (+)-Na -Demethylalstonisine, (-)-Alstonoxine A, and (+)-Alstonisine.
A highly enantio- and diastereoselective strategy to access any member of the sarpagine/macroline family of oxindole alkaloids… 
2015
2015
Efforts towards the Macrocyclic Core of Marineosin A and Development of Pyrrolidine-Based Scaffolds for Diversity-Oriented Synthesis
The total synthesis of marineosin A, a unique spiroaminal with selective cytotoxicity, has been under investigation in our… 
2015
2015
Enantiospecific Stereospecific Strategy for the Total Synthesis of Sarpagine and Macroline Related Oxindole Alkaloids: First Total Synthesis of Affinisine Oxindole, Isoalstonisine, Alstofoline…
2014
2014
Tuneable radical cyclisations: a tin-free approach towards tricyclic and spirocyclic heterocycles via a common precursor
A novel common precursor approach towards both tricyclic and spirocyclic heterocycles is described. Cyclisations are based on… 
2012
2012
Vasorelaxant activity of indole alkaloids from Tabernaemontana dichotoma
The aim of this study was to search for bioactive natural products from medicinal plants targeting vasorelaxant activity and we… 
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