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allylsilane

National Institutes of Health

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AlkenesSilanes

Papers overview

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2014
2014
Experimental and computational studies on interrupted Nazarov reactions: exploration of umpolung reactivity at the α-carbon of cyclopentanones.
A set of densely substituted, α-functionalized cyclopentanones can be generated by a two-component, domino reaction sequence… 
2008
2008
Synthesis of allylsilanes and dienylsilanes by a one-pot catalytic C-H borylation--Suzuki-Miyaura coupling sequence.
Allylsilane and various vinyl substrates undergo selective C-H bond functionalization based boronation reactions using iridium… 
2006
2006
Dual activation in asymmetric allylsilane addition to chiral N-acylhydrazones: method development, mechanistic studies, and elaboration of homoallylic amine adducts.
[reaction: see text] Chiral N-acylhydrazones derived from commercially available 4-benzyl-2-oxazolidinone provide a rigid… 
2006
2006
A monolithiated and its related 1,3-dilithiated allylsilane: syntheses, crystal structures, and reactivity.
Treatment of Me2Si(CH2CH=CH2)(CH2NC5H10) with 1 or 2 equiv of t-BuLi afforded the mono- or dilithiated allylsilanes, which… 
2005
2005
Synthesis of (+)-bullatacin via the highly diastereoselective [3+2] annulation reaction of a racemic aldehyde and a nonracemic allylsilane.
[reaction: see text] A total synthesis of (+)-bullatacin has been accomplished via a diastereoselective [3+2] annulation reaction… 
2004
2004
Reactivity control of an allylsilane bearing a 2-(phenylazo)phenyl group by photoswitching of the coordination number of silicon.
Photoswitching of the coordination number of silicon between four and five in allyldifluoro[2-(phenylazo)phenyl]silane, which was… 
Highly Cited
2002
Highly Cited
2002
Stereoselective total syntheses of the racemic form and the natural enantiomer of the marine alkaloid lepadiformine via a novel N-acyliminium ion/allylsilane spirocyclization strategy.
Stereoselective total syntheses of the racemic form and the natural enantiomer of the tricyclic marine alkaloid lepadiformine (6… 
2002
2002
Efficient synthesis of tetrasubstituted alkenes by allylsilane-terminated domino-Heck double cyclisation.
The domino-Heck double cyclisation of the arylbromides 1, which contain an allylsilane and an alkyne moiety and are easily… 
Highly Cited
2001
Highly Cited
2001
Synthetic Methodology for the Construction of Structurally Diverse Cyclopropanes
Practical and efficient routes for the stereoselective conversion of homoallylic alchols to diastereomerically pure cis-, trans-1… 
1995
1995
Stereoselective syntheses using carbohydrates as chiral auxiliaries
Abstract 
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