alkene monooxygenase activity

Known as: alkene epoxygenase activity, alkene,NADH:oxygen oxidoreductase activity

Catalysis of the reaction: propene + NADH + H+ + O2 = 1,2-epoxypropane + NAD+ + H2O. [EC:1.14.13.69]

National Institutes of Health

Papers overview

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2018

Asymmetric Copper-Catalyzed Defluoroalkylation

M. LautensA. Whyte
Synfacts
2018
Corpus ID: 106198522

Significance: Defluorination of trifluoromethyl alkenes has become a popular strategy in the past few years to introduce a new…

2017

New Reactivity Involving N-Isothiocyanates: Aminothiocarbonylation and [3+2] Cycloadditions to Form Molecules Containing NNCS Motifs

I. R. Gamage
2017
Corpus ID: 99801937

.................................................................................................................................................... ii Acknowledgements .............................................................................................................................. iv Chapter 1: Introduction ....................................................................................................................... 1 1.1 Cycloaddition Reactions Using Amphoteric Molecules ........................................................... 1 1.1.1 Related Amphoteric Molecules................................................................................................................ 1 1.2 NNCS Motifs Isolation and Reactivity of Isothiocyanates .................................................. 13 1.2.1 Importance of NNCS Motif ...................................................................................................................... 13 1.2.2 Importance of Isothiocyanates ............................................................................................................. 14 1.2.3 Synthesis of N-isothiocyanates............................................................................................................. 16 1.2.4 Reactivity of Isothiocyanates vs Isocyanates ................................................................................. 19 1.3 NNCS Motifs – Preliminary Results for Alkene Aminothiocarbonylation ..................... 25 1.3.1 Fluorenone Based Precursor Formation.......................................................................................... 25 1.3.2 Enol Ether Aminothiocarbonylation .................................................................................................. 28 1.3.3 Derivatization of Thioxo-azomethine Imines ................................................................................ 29 1.4 Research Objectives .......................................................................................................................... 30 Chapter 2: Aminothiocarbonylation .............................................................................................31 2.

2015

Synthesis of Azomethine Imines via Alkene Aminocarbonylation and their Derivatization into Pyrazolones

K. Lavergne
2015
Corpus ID: 99947567

.................................................................................................................................................. ii Aknowledgements ................................................................................................................................. iii List of Abbreviations ...............................................................................................................................vi List of Figures ........................................................................................................................................ viii List of Schemes ....................................................................................................................................... ix List of Tables ............................................................................................................................................ x Chapter 1: Alkene Aminocarbonylation in Heterocyclic synthesis ....................................................... 1 1.1 Aminocarbonylation ...................................................................................................................... 3 1.1.1 Metal-Catalyzed Aminocarbonylation in Heterocyclic synthesis ........................................... 4 1.1.2 Alkene Aminocarbonylation with Chlorosulfonyl-isocyanate .............................................. 10 1.2 N-Substituted isocyanates .......................................................................................................... 11 1.3 Alkene Aminocarbonylation with imino-isocyanates ................................................................. 17 1.3.1 Investigation into Base Catalysis ......................................................................................... 18 1.4 Project Objectives ........................................................................................................................ 21 Chapter 2: Development of Mild Alkene Aminocarbonylation ........................................................... 22 2.1 Base Catalysis: Optimization with Dihydrofuran ......................................................................... 22 2.2 Extension of scope for base catalysis .......................................................................................... 24 2.3 Alkene Aminocarbonylation with enol ethers ............................................................................ 26 2.4 Alkene aminocarbonylation with enamines ............................................................................... 32 2.5 Exploration of base catalysis on intramolecular aminocarbonylation reactions ........................ 34 2.6 Conclusions for Chapter 2 ............................................................................................................ 38 Chapter 3: Synthesis of Pyrazolones .................................................................................................... 40 3.