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acetomycin

Known as: 3-acetyl-5-(acetyloxy)dihydro-3,4-dimethyl-2(3H)furanone 
National Institutes of Health

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2009
2009
Hans Zähner(7 June 1929–18 December 2008)
Professor Hans Zähner passed away on 18 December 2008 at the age of 79 after a prolonged illness. Hans Zähner was born on 7 June… 
2007
2007
Formation of chiral quaternary carbon stereocenters using silylene transfer reactions: enantioselective synthesis of (+)-5-epi-acetomycin.
Chiral quaternary carbon stereocenters can be established with high diastereoselectivity by a silylene transfer/Ireland-Claisen… 
2006
2006
ACTIVITY AGAINST TUMOR CELLS IN VITRO AND IN VIVO
Theantibiotic acetomycinwasactive in vitro against HCT-8humancolon adenocarcinoma cells (IC50, 1.5 ^g/ml) and L1210 murine… 
1999
1999
Total synthesis of (+/-)-acetomycin and design of esterase-resistant analogs.
The synthesis of acetomycin and related analogs was investigated. Acetomycin was synthesized from diethyl allyl(methyl)malonate… 
1988
1988
The structure and absolute configuration of acetomycin.
C10H14O5, Mr = 214.22, orthorhombic, P2(1)2(1)2(1), a = 14.1084 (6), b = 10.6443 (3), c = 7.1970 (1) A, V = 1080.80 (6) A3, Z = 4… 
1987
1987
Biological effects of acetomycin. II. Inactivation by esterases in vitro.
Acetomycin has antitumor activity in vitro but not in vivo. HCT-8 human colon adenocarcinoma assays in the presence of a drug… 
1987
1987
Biological effects of acetomycin. I. Activity against tumor cells in vitro and in vivo.
The antibiotic acetomycin was active in vitro against HCT-8 human colon adenocarcinoma cells (IC50, 1.5 microgram/ml) and L1210… 
1985
1985
The structure of acetomycin. Spectroscopic characterization and X-ray analysis of a bromo derivative.
Acetomycin (1a), known since 1958, has been further characterized by NMR and CD spectra. The 3-acetyl side chain of 1a is reduced… 
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