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Nitroalkanes

Known as: nitroalkane 
National Institutes of Health

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2 relations

Broader (2)

AlkanesNitro Compounds

Papers overview

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Highly Cited
2013
Highly Cited
2013
Electrochemical synthesis of the aryl α-ketoesters from acetophenones mediated by KI.
This anodic oxidation of acetophenones in the presence of methanol or ethanol not only provides a simple approach to α-ketoester… 
Highly Cited
2010
Highly Cited
2010
Chiral Brønsted base-promoted nitroalkane alkylation: enantioselective synthesis of sec-alkyl-3-substituted indoles.
A Brønsted base-catalyzed reaction of nitroalkanes with alkyl electrophiles provides indole heterocycles substituted at C3… 
Review
2009
Review
2009
Asymmetric organocatalysis by chiral Brønsted bases: implications and applications.
Chiral, metal-free Brønsted bases have been demonstrated capable of catalyzing several types of C-C and C-X bond-forming… 
Highly Cited
2009
Highly Cited
2009
Enantioselective Henry (nitroaldol) reaction catalyzed by axially chiral guanidines.
Highly Cited
2008
Highly Cited
2008
Highly enantioselective direct Michael addition of nitroalkanes to nitroolefins catalyzed by La(OTf)3/N,N'-dioxide complexes.
The conjugate addition of carbon nucleophiles to nitroalkenes is an important synthetic process in organic synthesis mainly… 
Highly Cited
2008
Highly Cited
2008
Asymmetric nitroaldol reaction catalyzed by a C2-symmetric bisoxazolidine ligand.
A C2-symmetric bisoxazolidine was found to effectively catalyze the asymmetric Henry reaction of aliphatic and aromatic aldehydes… 
2005
2005
Solvent polarization and kinetic isotope effects in nitroethane deprotonation and implications to the nitroalkane oxidase reaction.
We have carried out a mixed molecular dynamics and centroid path integral simulation using a combined quantum mechanical and… 
2003
2003
Nitroalkanes in aqueous medium as an efficient and eco-friendly source for the one-pot synthesis of 1,4-diketones, 1,4-diols, delta-nitroalkanols, and hydroxytetrahydrofurans.
The Michael addition of primary aliphatic nitro compounds to alpha,beta-unsaturated enones, performed in aqueous media, provides… 
1998
1998
Carbanion Stabilization by Adjacent Sulfur: Polarizability, Resonance, or Negative Hyperconjugation? Experimental Distinction Based on Intrinsic Rate Constants of Proton Transfer from (Phenylthio…
(Phenylthio)nitromethane, PhSCH2NO2, is about as acidic as PhCH2NO2 and about 4 pKa-units more acidic than CH3NO2 in water or… 
Highly Cited
1977
Highly Cited
1977
Nitrosoalkanes as Fe(II) ligands in the 455-nm-absorbing cytochrome P-450 complexes formed from nitroalkanes in reducing conditions.
Primary and secondary aliphatic nitroalkanes RR'CHNO2, react with microsomal cytochrome p-450 in the presence of dithionite… 
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