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Cycloalkynes

Known as: Cyclic Acetylenes, cycloalkyne 
National Institutes of Health

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Broader (1)

Cycloparaffins

Papers overview

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2014
2014
Total synthesis of the biphenyl alkaloid (-)-lythranidine.
A sequence comprising a ring-closing alkyne metathesis of a propargyl alcohol derivative, followed by a ruthenium-catalyzed redox… 
2011
2011
Generation of medium-ring cycloalkynes by ring expansion of vinylogous acyl triflates.
Reductive cyclization of aryl and vinyl iodides tethered to vinylogous acyl triflates (VATs) induces a ring-expanding… 
Highly Cited
2008
Highly Cited
2008
Transformation of a 1-zirconacyclopent-3-yne, a five-membered cycloalkyne, into a 1-zirconacyclopent-3-ene and formal "1-zirconacyclopenta-2,3-dienes".
2006
2006
Stereoselective synthesis of eight-membered cyclic ethers by tandem Nicholas reaction/ring-closing metathesis: a short synthesis of (+)-cis-Lauthisan.
Cis-2,8-disubstituted oxocanes and the parent unsaturated precursors were prepared from the corresponding Co2(CO)6-cycloalkynic… 
2005
2005
Generation of cycloalkynes by hydro-iodonio-elimination of vinyl iodonium salts.
Cyclohexynes can be generated efficiently from 1-cyclohexenyliodonium salts with acetate or other bases via the E2 and E1… 
Highly Cited
2002
Highly Cited
2002
A chemo- and stereoselective reduction of cycloalkynes to (E)-cycloalkenes.
A stereoselective entry into (E)-cycloalkenes is described, comprising the ring closing alkyne metathesis (RCAM) of suitable… 
2001
2001
The electron as a protecting group. 3. Generation of acenaphthyne radical anion and the determination of the heat of formation of a strained cycloalkyne.
Acenaphthyne dicarboxylate (12) was transferred into the gas phase from solution via electrospray ionization and subsequently was… 
Highly Cited
1998
Highly Cited
1998
Ring-Closing Metathesis of Functionalized Acetylene Derivatives: A New Entry into Cycloalkynes.
A tungsten alkylidyne catalyst is the key to achieving ring-closing metatheses of diynes to form functionalized macrocycles [Eq… 
1997
1997
Dehydrocyclooctatetraene. Photoelectron Spectroscopy of the C8H6 Anion
The photoelectron spectrum of the dehydrocyclooctatetraene negative ion, C8H6-, is reported. The spectrum strongly resembles that… 
1989
1989
The stabilization and reactivity of strained cyclic alkynes on transition metal centres
Abstract 
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