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Cumulenes

Compounds with four adjacent carbons joined by double bonds.
National Institutes of Health

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1 relation

Broader (1)

Polyenes

Papers overview

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2018
2018
Carbene derived diradicaloids – building blocks for singlet fission?
Carbene–bridge–carbene ensembles: tunable diradicaloids for singlet fission? 
2014
2014
Insights into chromatographic enantiomeric separation of allenes on cellulose carbamate stationary phase.
2011
2011
Asymmetric addition of arylboronic acids to cumulene derivatives catalyzed by axially chiral N-heterocyclic carbene-Pd2+ complexes.
The method affords allenes which can be further transformed on a 2 mmol scale into dihydropyrans or an aldehyde without loss of… 
Highly Cited
2008
Highly Cited
2008
1,3-Diethynylallenes (DEAs): enantioselective synthesis, absolute configuration, and chiral induction in 1,1,4,4-tetracyanobuta-1,3-dienes (TCBDs).
In 1875 van t Hoff predicted that in cumulenes with an even number of double bonds the four substituents must be arranged in two… 
Review
2005
Review
2005
3 Mass spectrometry of free radicals: a methodological overview
This review outlines the advances that have been made in the area of mass spectrometric investigations of gas-phase radicals, and… 
2004
2004
DNA-directed alkylating agents: synthesis, antitumor activity and DNA affinity of bis-N,N'-trisubstituted 1,2,4-triazolo-piperazines.
2002
2002
Synergism of catalysis and reaction center rehybridization in nucleophilic additions to cumulenes: the one-, two-, three-water hydrolyses of carbodiimide and methyleneimine.
The results of a theoretical study of the one-, two- and three-water hydrolyses of carbodiimide and the one- and two-water… 
2000
2000
Structure and stability of enediynes containing heteroatoms—a quantum chemical investigation
Highly Cited
2000
Highly Cited
2000
Heavy allenes and cumulenes e=c=e' and e=c=c=e' (e = p, as, si, ge, sn; e' = C, N, p, as, o, s).
1991
1991
Unusual molecules - unusual reactions from tetra-tert-butyl-tetrahedrane to the dimer of carbon sulfide
Abstract 
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