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Bi(OTf)3

Known as: bismuth triflate 
National Institutes of Health

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1 relation

Broader (1)

Mesylates

Papers overview

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Review
2012
Review
2012
Facile coupling of propargylic, allylic and benzylic alcohols with allylsilane and alkynylsilane, and their deoxygenation with Et3SiH, catalyzed by Bi(OTf)3 in [BMIM][BF4] ionic liquid (IL), with…
Allyltrimethylsilane (allyl-TMS) reacts with propargylic alcohols 1a-1d in the presence of 10% Bi(OTf)(3) in [BMIM][BF(4… 
2011
2011
Biomimetic cationic polyannulation reaction catalyzed by Bi(OTf)3: cyclization of 1,6-dienes, 1,6,10-trienes, and aryl polyenes.
Nonactivated trienes and aryltrienes were cyclized into polycyclic compounds in good to excellent yields under bismuth triflate… 
2011
2011
Synthesis of chiral 1-substituted tetrahydroisoquinolines by the intramolecular 1,3-chirality transfer reaction catalyzed by Bi(OTf)3.
The intramolecular 1,3-chirality transfer reaction of chiral amino alcohols 1 with 99% ee was developed to construct chiral 1… 
2011
2011
Electrophilic chemistry of propargylic alcohols in imidazolium ionic liquids: propargylation of arenes and synthesis of propargylic ethers catalyzed by metallic triflates [Bi(OTf)3, Sc(OTf)3, Yb(OTf…
Metallic triflates M(OTf)(3) (M = Bi, Sc, Yb), immobilized in imidazolium ionic liquids [BMIM][BF(4)], [BMIM][PF(6)] and [BMIM… 
2011
2011
Tandem ene-reaction/hydroamination of amino-olefin and -allene compounds catalyzed by Bi(OTf)3.
Bi(OTf)(3) was proven to act as an effective catalyst for tandem ene-reaction/hydroamination of amino-olefin and amino-allene… 
2009
2009
Intramolecular alkynylcyclopropanation of olefins catalyzed by Bi(OTf)3: stereoselective synthesis of 1-alkynyl-3-azabicyclo[3.1.0]hexanes.
The development of efficient cyclization methods for the construction of nitrogen-containing heterocycles constitutes an ongoing… 
Highly Cited
2008
Highly Cited
2008
Bismuth-catalyzed intramolecular carbo-oxycarbonylation of 3-alkynyl esters.
Borderline metal complexes, especially Bi(OTf)3, efficiently catalyze the carbo-oxycarbonylation of alkynyl esters to form… 
Highly Cited
2007
Highly Cited
2007
An efficient and mild bismuth triflate-catalysed three-component Mannich-type reaction.
In the presence of a catalytic amount of Bi(OTf)(3).4H(2)O, aldehydes together with amines react with silyl enolates to afford… 
Highly Cited
2005
Highly Cited
2005
Bismuth triflate-chiral bipyridine complexes as water-compatible chiral Lewis acids.
[reaction: see text] Catalytic asymmetric hydroxymethylation of silicon enolates with an aqueous formaldehyde solution has been… 
Highly Cited
2002
Highly Cited
2002
Bismuth triflate catalyzed allylation of acetals: a simple and mild method for synthesis of homoallyl ethers
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