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BINOLAM

National Institutes of Health

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BINAP, 2-naphthol

Papers overview

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2011
2011
Mechanistic studies on the enantioselective BINOLAM/titanium(IV)-catalyzed cyanobenzoylation of aldehydes: Part 1
2010
2010
[Ln(binolam)3]·(OTf)3, a new class of propeller-shaped lanthanide(III) salt complexes as enantioselective catalysts: structure, dynamics and mechanistic insight.
The ligand 3,3'-bis(diethylaminomethyl)-1,1'-bi-2-naphthol (binolam) contains an arrayed Brønsted acid-Brønsted base (BABB… 
2009
2009
Lanthanide (III) salt complexes: arrayed acid-base networks for enantioselective catalysis. The nitroaldol reaction upon aldehydes and trifluoromethylketones.
Shelf stable, chiral-at-metal, D(3) symmetric, 3:1 complexes of lanthanide (III) triflate salts are easily available by… 
2007
2007
Enantioenriched cyanohydrin O-phosphates: Synthesis and applications as chiral building blocks
Abstract Aluminum complexes of the chiral (R)- or (S)-3,3'-bis(diethylaminomethyl)-1,1'-bi-2,2'-naphthol (BINOLAM) ligand behave… 
2005
2005
Binolam-AlCl: a two-centre catalyst for the synthesis of enantioenriched cyanohydrin O-phosphates.
The enantioselective synthesis of cyanohydrin O-phosphates by using in situ generated bifunctional catalysts (R)- or (S)-3,3'-bis… 
Highly Cited
2002
Highly Cited
2002
BINOLAM, a recoverable chiral ligand for bifunctional enantioselective catalysis: the asymmetric synthesis of cyanohydrins.
[reaction: see text] A new bifunctional catalytic system based on a monometallic aluminum complex is used for the efficient… 
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