4-(dimethylamino)pyridine
National Institutes of Health
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Rate and equilibrium constants for the reactions of pyridines with donor-substituted benzhydrylium ions have been determined…
The acetylation of tert-butanol with acetic anhydride catalyzed by 4-(dimethylamino)pyridine (DMAP) has been studied at the…
Gold nanoparticles stabilized with 4-(dimethylamino)pyridine (DMAP) were prepared by ligand exchange and phase transfer (toluene…
Whereas chiral Lewis acid catalysis has been intensively investigated, chiral Lewis base (nucleophilic) catalysis has been…
Various carboxylic esters are obtained at room temperature in excellent yields with high chemoselectivities from nearly equimolar…
A metal-free approach to the living ring-opening polymerization (ROP, shown schematically) of lactide has been developed using…
The reaction of BOC2O in the presence and absence of DMAP was examined with some amines, alcohols, diols, amino alcohols, and…
A concise seven-step synthesis of atropisomeric 3-aryl analogues of DMAP from 4-pyridone 8 has been developed. A representative…
(−)-Galanthamine has been synthesised using an efficient nine-step procedure, which in large scale affords 12.4 (6.7−19.1…