2,2,6,6-tetramethylpiperidide

A metal-free catalyst born of frustration Boron (a Lewis acid) and nitrogen or phosphorus fragments (both Lewis bases) tend to… Expand

Reaction of 1 with B(C6F5)3 under 1 bar of CO2 led to the instantaneous formation of the frustrated Lewis pair (FLP)-type species… Expand

Heteroarenes equipped with aryl groups (heterobiaryls) are often found in biologically active compounds, organic materials, and… Expand

The frustrated Lewis pair system consisting of 2 equiv of 2,2,6,6-tetramethylpiperidine (TMP) and tris(pentafluorophenyl)borane… Expand

In the presence of 2,2,6,6-tetramethylpiperidine (TMP) 1,8-bis(dipentafluorophenylboryl)naphthalene has been found to activate H2… Expand

In industrially important reactions, such as hydroformylation and hydrogenation, H2 gas serves as a reducing agent and/or a… Expand

Pyruvate ferredoxin oxidoreductase (PFOR), which catalyzes the oxidative decarboxylation of pyruvate to form acetyl-CoA and CO2… Expand

Exposure of isolated spinach thylakoids to high intensity illumination (photoinhibition) results in the well-characterized… Expand

The mechanistic aspects of the cyclization of (2-ethynylphenyl)triazenes under both thermal and copper-mediated conditions are… Expand

Summary. Molecular oxygen in electronic singlet state is a very powerful oxidant. Its damaging action in a variety of biological… Expand