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2,2,6,6-tetramethylpiperidide

Known as: 2,2,6,6-tetramethylpiperidine 
 
National Institutes of Health

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Highly Cited
2015
Highly Cited
2015
A metal-free catalyst born of frustration Boron (a Lewis acid) and nitrogen or phosphorus fragments (both Lewis bases) tend to… Expand
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Highly Cited
2013
Highly Cited
2013
Reaction of 1 with B(C6F5)3 under 1 bar of CO2 led to the instantaneous formation of the frustrated Lewis pair (FLP)-type species… Expand
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Highly Cited
2011
Highly Cited
2011
Heteroarenes equipped with aryl groups (heterobiaryls) are often found in biologically active compounds, organic materials, and… Expand
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Highly Cited
2010
Highly Cited
2010
The frustrated Lewis pair system consisting of 2 equiv of 2,2,6,6-tetramethylpiperidine (TMP) and tris(pentafluorophenyl)borane… Expand
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Highly Cited
2009
Highly Cited
2009
In the presence of 2,2,6,6-tetramethylpiperidine (TMP) 1,8-bis(dipentafluorophenylboryl)naphthalene has been found to activate H2… Expand
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Highly Cited
2008
Highly Cited
2008
In industrially important reactions, such as hydroformylation and hydrogenation, H2 gas serves as a reducing agent and/or a… Expand
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Highly Cited
2008
Highly Cited
2008
Pyruvate ferredoxin oxidoreductase (PFOR), which catalyzes the oxidative decarboxylation of pyruvate to form acetyl-CoA and CO2… Expand
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Highly Cited
2004
Highly Cited
2004
Exposure of isolated spinach thylakoids to high intensity illumination (photoinhibition) results in the well-characterized… Expand
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Highly Cited
2002
Highly Cited
2002
The mechanistic aspects of the cyclization of (2-ethynylphenyl)triazenes under both thermal and copper-mediated conditions are… Expand
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Highly Cited
2001
Highly Cited
2001
Summary. Molecular oxygen in electronic singlet state is a very powerful oxidant. Its damaging action in a variety of biological… Expand
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