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2,2,6,6-tetramethylpiperidide

Known as: 2,2,6,6-tetramethylpiperidine 
National Institutes of Health

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1 relation

Broader (1)

Piperidines

Papers overview

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Review
2018
Review
2018
Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions.
N-Oxyl compounds represent a diverse group of reagents that find widespread use as catalysts for the selective oxidation of… 
Highly Cited
2015
Highly Cited
2015
Metal-free catalytic C-H bond activation and borylation of heteroarenes
A metal-free catalyst born of frustration Boron (a Lewis acid) and nitrogen or phosphorus fragments (both Lewis bases) tend to… 
Highly Cited
2014
Highly Cited
2014
Scope and limitations of the TEMPO/EPR method for singlet oxygen detection: the misleading role of electron transfer.
Highly Cited
2013
Highly Cited
2013
Catalytic CO2 activation assisted by rhenium hydride/B(C6F5)3 frustrated Lewis pairs--metal hydrides functioning as FLP bases.
Reaction of 1 with B(C6F5)3 under 1 bar of CO2 led to the instantaneous formation of the frustrated Lewis pair (FLP)-type species… 
Highly Cited
2011
Highly Cited
2011
Oxidative biaryl coupling of thiophenes and thiazoles with arylboronic acids through palladium catalysis: otherwise difficult C4-selective C-H arylation enabled by boronic acids.
Heteroarenes equipped with aryl groups (heterobiaryls) are often found in biologically active compounds, organic materials, and… 
Highly Cited
2010
Highly Cited
2010
Tandem frustrated Lewis pair/tris(pentafluorophenyl)borane-catalyzed deoxygenative hydrosilylation of carbon dioxide.
The frustrated Lewis pair system consisting of 2 equiv of 2,2,6,6-tetramethylpiperidine (TMP) and tris(pentafluorophenyl)borane… 
Highly Cited
2009
Highly Cited
2009
Metal-free hydrogen activation and hydrogenation of imines by 1,8-bis(dipentafluorophenylboryl)naphthalene.
In the presence of 2,2,6,6-tetramethylpiperidine (TMP) 1,8-bis(dipentafluorophenylboryl)naphthalene has been found to activate H2… 
Highly Cited
2008
Highly Cited
2008
Facile heterolytic H2 activation by amines and B(C6F5)3.
In industrially important reactions, such as hydroformylation and hydrogenation, H2 gas serves as a reducing agent and/or a… 
Highly Cited
2008
Highly Cited
2008
Biomimetic carbene-catalyzed oxidations of aldehydes using TEMPO.
Pyruvate ferredoxin oxidoreductase (PFOR), which catalyzes the oxidative decarboxylation of pyruvate to form acetyl-CoA and CO2… 
Highly Cited
2001
Highly Cited
2001
Effect of proline on the production of singlet oxygen
Summary. Molecular oxygen in electronic singlet state is a very powerful oxidant. Its damaging action in a variety of biological… 
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