vinylcarbene
National Institutes of Health
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Non-fluorinated vinyldiazo compounds with trans-configuration irrespective of the nature of 3-R(1)-substituent (R(1) = H, Me…
Synthesis of a sterically congested metallacyclobutene complex has led to the first observation of metallacyclobutene-η(3…
With metal carbene access to dipolar intermediates, 3,6-dihydro-1,2-oxazines are produced in high yields by dirhodium(II…
The reaction of carbonyl-ene-nitrile compounds with propargyl carboxylates in the presence of a catalytic amount of PtCl(2…
The stabilization energy provided by resonance in singlet and triplet vinylcarbenes is evaluated using density functional and G3…
Dichloro- and phenylchlorocarbene (CCl2 and PhCCl) add to cyclooctyne via a barrierless process (MP2/6-311+G*, B3LYP/6-311+G…
The mechanisms of photochemical isomerization reactions were investigated theoretically using the following model systems: spiro…
The preparation, structure, and catalytic activity of a series of bidentate η1-vinylcarbene ruthenium complexes derived from the…