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trimethyl(trifluoromethyl)silane

Known as: TMSCF(3), TMSCF3 
National Institutes of Health

Related topics

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2 relations

Broader (2)

Hydrocarbons, FluorinatedSilanes

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2016
2016
Phenyliodonium diacetate mediated carbotrifluoromethylation of N-acylhydrazones.
A concise, efficient and direct trifluoromethylation method of aldehyde-derived N-acylhydrazones has been firstly developed by… 
2014
2014
Oxidative nucleophilic strategy for synthesis of thiocyanates and trifluoromethyl sulfides from thiols.
Thiocyanates and trifluoromethyl sulfides are important compounds and have classically been synthesized via multistep procedures… 
2012
2012
Room Temperature Aryl Trifluoromethylation via Copper-Mediated
A method for the room temperature copper-mediated trifluoromethylation of aryl and heteroaryl boronic acids has been developed… 
2008
2008
High-Pressure Freezing, Crystal Structure Studies and Si-CF3 Bond Polarizability of Trimethyl(trifluoromethyl)silane (Postprint)
2008
2008
An efficient entry to optically active anti- and syn-beta-amino-alpha-trifluoromethyl alcohols.
The reaction of chiral 5,6-dihydro-2H-1,4-oxazin-2-ones with TMSCF3 in the presence of a suitable activator leads to… 
2005
2005
How trimethyl(trifluoromethyl)silane reacts with itself in the presence of naked fluoride--a one-pot synthesis of bis([15]crown-5)cesium 1,1,1,3,5,5,5-heptafluoro-2,4-bis(trifluoromethyl)pentenide.
Reactions of trimethyl(trifluoromethyl)silane in the presence of "naked" fluoride proceed up to a temperature of +5 degrees C… 
2001
2001
Stereoselective Nucleophilic Trifluoromethylation of N-(tert-Butylsulfinyl)imines by Using Trimethyl(trifluoromethyl)silane Support of our work by Loker Hydrocarbon Research Institute is gratefully…
Highly Cited
1998
Highly Cited
1998
Direct Preparation of Trifluoromethyl Ketones from Carboxylic Esters: Trifluoromethylation with (Trifluoromethyl)trimethylsilane.
Previously difficult to prepare, aliphatic and alicyclic trifluoromethylketones (e.g. 1 and 2), which are of pharmacalogic… 
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