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trimethyl(trifluoromethyl)silane
Known as:
TMSCF(3)
, TMSCF3
National Institutes of Health
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Related topics
Related topics
2 relations
Broader (2)
Hydrocarbons, Fluorinated
Silanes
Papers overview
Semantic Scholar uses AI to extract papers important to this topic.
2016
2016
Phenyliodonium diacetate mediated carbotrifluoromethylation of N-acylhydrazones.
Weigang Zhang
,
Yingpeng Su
,
+5 authors
Yulai Hu
Organic and biomolecular chemistry
2016
Corpus ID: 23369278
A concise, efficient and direct trifluoromethylation method of aldehyde-derived N-acylhydrazones has been firstly developed by…
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2014
2014
Oxidative nucleophilic strategy for synthesis of thiocyanates and trifluoromethyl sulfides from thiols.
K. Yamaguchi
,
Konomi Sakagami
,
Y. Miyamoto
,
Xiongjie Jin
,
N. Mizuno
Organic and biomolecular chemistry
2014
Corpus ID: 13861713
Thiocyanates and trifluoromethyl sulfides are important compounds and have classically been synthesized via multistep procedures…
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2012
2012
Room Temperature Aryl Trifluoromethylation via Copper-Mediated
D. Sénécal
,
A. T. Parsons
2012
Corpus ID: 41425729
A method for the room temperature copper-mediated trifluoromethylation of aryl and heteroaryl boronic acids has been developed…
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2008
2008
High-Pressure Freezing, Crystal Structure Studies and Si-CF3 Bond Polarizability of Trimethyl(trifluoromethyl)silane (Postprint)
A. Olejniczak
,
A. Katrusiak
,
A. Vij
2008
Corpus ID: 53650093
2008
2008
An efficient entry to optically active anti- and syn-beta-amino-alpha-trifluoromethyl alcohols.
S. Fustero
,
L. Albert
,
J. Aceña
,
J. F. Sanz-Cervera
,
A. Asensio
Organic Letters
2008
Corpus ID: 13269599
The reaction of chiral 5,6-dihydro-2H-1,4-oxazin-2-ones with TMSCF3 in the presence of a suitable activator leads to…
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2005
2005
How trimethyl(trifluoromethyl)silane reacts with itself in the presence of naked fluoride--a one-pot synthesis of bis([15]crown-5)cesium 1,1,1,3,5,5,5-heptafluoro-2,4-bis(trifluoromethyl)pentenide.
W. Tyrra
,
M. M. Kremlev
,
+5 authors
Y. Yagupolskii
Chemistry
2005
Corpus ID: 39454095
Reactions of trimethyl(trifluoromethyl)silane in the presence of "naked" fluoride proceed up to a temperature of +5 degrees C…
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2001
2001
Stereoselective Nucleophilic Trifluoromethylation of N-(tert-Butylsulfinyl)imines by Using Trimethyl(trifluoromethyl)silane Support of our work by Loker Hydrocarbon Research Institute is gratefully…
G. Prakash
,
M. Mandal
,
G. Olah
Angewandte Chemie
2001
Corpus ID: 263446446
Highly Cited
1998
Highly Cited
1998
Direct Preparation of Trifluoromethyl Ketones from Carboxylic Esters: Trifluoromethylation with (Trifluoromethyl)trimethylsilane.
J. Wiedemann
,
Thomas Heiner
,
G. Mloston
,
G. Prakash
,
G. Olah
Angewandte Chemie
1998
Corpus ID: 14020705
Previously difficult to prepare, aliphatic and alicyclic trifluoromethylketones (e.g. 1 and 2), which are of pharmacalogic…
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