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titanium ate enolate

 
National Institutes of Health

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2016
2016
Rh(iii)-catalyzed cascade addition of C–H bonds across alkene and carbonyl π-bonds to form two new σ C–C bonds is accomplished. 
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Highly Cited
2013
Highly Cited
2013
NHC-enolate plus 3: N-heterocyclic carbenes (NHCs) serve as organocatalysts for the [2+3] annulation of nitrovinylindoles with… Expand
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Highly Cited
2012
Highly Cited
2012
The formation of all-carbon quaternary stereocentres in acyclic systems is one of the most difficult contemporary challenges in… Expand
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2012
2012
The a-arylation of enolates has become a widely used method to prepare a-aryl carboxylic acid and ketone derivatives that… Expand
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Highly Cited
2011
Highly Cited
2011
The recent development of new gold(I) catalysis methodologies has opened the door to new disconnections for the total synthesis… Expand
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2011
2011
The reaction of enol(ate)s with electrophiles is used extensively in organic synthesis for stereoselective C-C bond formation… Expand
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Highly Cited
2008
Highly Cited
2008
In this Communication, we disclose a catalytic, highly enantioselective (up to >99% ee) alpha-fluorination of acid chlorides to… Expand
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2008
2008
We report a detailed synthetic and mechanistic study of an unusual bifunctional, sequential hetero-Diels-Alder/ring-opening… Expand
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Highly Cited
2005
Highly Cited
2005
The radical trifluoromethylation of ketone titanium ate enolates gave alpha-CF3 ketones in good yields. The use of excess amount… Expand
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Highly Cited
2004
Highly Cited
2004
Exposure of enones and enals to 20 mol % tributylphosphine in the presence of triarylbismuth(V) dichlorides results in… Expand
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