sinenxan A
National Institutes of Health
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以生物合成的SinenxanA(SIA)为起始物,在合成1,7,9-trideoxytaxol的路线中,化合物1为关键中间体,研究了以多种不同氧化剂、在不同条件下[1,2],对14-deoxy-SIA的13…
14-Deacetoxy-13-oxo sinenxan A (1) was converted to 9α-hydroxy-13-oxo-2α, 5α, 10β-triacetoxy-4(20),11-taxadiene (2) and 10…