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silanone

 
National Institutes of Health

Papers overview

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2017
2017
A long-term dream comes true: An acyclic, neutrally charged silanone at last! Here, we report on the first examples of isolable… Expand
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2015
2015
We report the evaporation of a stable cyclic silylene and its oxidation (with ozone or N2 O) through oxygen atom transfer to form… Expand
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Highly Cited
2014
Highly Cited
2014
SiO in a complex: The first silanone that is stable at room temperature (3) is reported. The two-step synthesis involves… Expand
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2014
2014
Mission accomplished: More than 100 years after first attempts at isolating a stable silanone, this task has finally been… Expand
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2011
2011
Base-stabilized silanone complex Cp*(OC)(2)W(SiMe(3)){O═SiMes(2)(DMAP)} (2) was synthesized by the reaction of (silyl)(silylene… Expand
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2011
2011
The first donor-stabilized silylated silicoxonium species [LSi=O-SiMe(3)](+) (L=(RN)C(=CH(2))CH=CMe(NR), R=2,6-iPr(2)C(6)H(3… Expand
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Highly Cited
2010
Highly Cited
2010
A series of N-heterocyclic carbene-stabilized silanechalcogenones 2 a,b (Si=O), 3 a,b (Si=S), 4 a,b (Si=Se), and 5 a,b (Si=Te… Expand
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Highly Cited
2009
Highly Cited
2009
The unique isolable silanone complex 3 has been synthesized and isolated in 94% yield by the remarkably facile oxygenation of the… Expand
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2009
2009
The optical absorption spectrum and lowest photoluminescence (PL) signal for silanone terminated silica nanostructures are… Expand
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2002
2002
Infrared-absorption measurements and first-principles quantum chemical calculations reveal that the initial oxidation of clean… Expand
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