phosphinine
National Institutes of Health
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The [4+2] cycloaddition reaction between 2-pyrone and Me3 Si-C≡P gives the corresponding 2-(trimethylsilyl)-λ3 -phosphinine in…
Gold(i) complexes based on a 2,4,6-triarylphosphinine and a mesoionic carbene derivative have been prepared and characterized…
A hitherto unprecedented electronic situation has been observed for a substituted, pyridyl-functionalized phosphinine. In…
Access to homoleptic phosphinine-based coordination compounds of d(6) metals has so far remained elusive. We report here on the…
The design and preparation of an asymmetrically substituted and bulky phosphinine was achieved by introducing sterically…
Phosphinines belong to an intriguing class of phosphorus-containing heterocycles with interesting steric, electronic and…
The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the…
The first synthesis of gold nanoparticles stabilised by a sub-stoichiometric amount of sp(2) phosphorus containing ligands was…
A new class of phosphinine/rhodium catalysts for the hydroformylation of terminal and internal alkenes is presented in this study…
Chemical and electrochemical reductions of the macrocycle 1 lead to the formation of a radical monoanion anion [1](*)(-) whose…