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phosphinine

 
National Institutes of Health

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2019
2019
A series of substituted phosphinines, 1-phosphabarrelenes and 5-phosphasemibullvalenes were synthesized and evaluated for their… Expand
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2018
2018
The [4+2] cycloaddition reaction between 2-pyrone and Me3 Si-C≡P gives the corresponding 2-(trimethylsilyl)-λ3 -phosphinine in… Expand
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2014
2014
A hitherto unprecedented electronic situation has been observed for a substituted, pyridyl-functionalized phosphinine. In… Expand
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2013
2013
Access to homoleptic phosphinine-based coordination compounds of d(6) metals has so far remained elusive. We report here on the… Expand
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2012
2012
The first phosphinine 2-carboxaldehyde was synthesized as shown and transformed into an alkene via a Wittig reaction without… Expand
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2007
2007
Phosphinines belong to an intriguing class of phosphorus-containing heterocycles with interesting steric, electronic and… Expand
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2007
2007
The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the… Expand
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2004
2004
The first synthesis of gold nanoparticles stabilised by a sub-stoichiometric amount of sp(2) phosphorus containing ligands was… Expand
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2001
2001
Chemical and electrochemical reductions of the macrocycle 1 lead to the formation of a radical monoanion anion [1](*)(-) whose… Expand
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1999
1999
A "CO-like matrix", showing coordination analogous to that of carbonyl groups, is provided by silacalix[4]phosphinine macrocycles… Expand
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