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In the presence of CsF, a wide range of α-substituted α-siloxy silanes were carboxylated under a CO2 atmosphere (1 atm) via Brook… Expand An efficient and flexible route for the synthesis of α-tertiary (α,α-dibranched) α-silylamines via sequential reactions of… Expand Phenyldimethylsilyllithium reacts with N,N-dimethylamides in a variety of ways, depending upon the stoichiometry, the temperature… Expand Phenyldimethylsilyllithium reacts with N-phenylpyrrolidone 5 to give the known tetracyclic amines [2,3,3a,3b,4,5,6,11b-octahydro… Expand Phenyldimethylsilyllithium reacts with several N,N-dimethylamides, and the intermediates, formulated here as successively a… Expand Phenyldimethylsilyllithium reacts with the beta-N,N-dimethylaminoenones 1 and 7, with the enal 5, and with ethyl beta-N,N… Expand