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phenyldimethylsilyllithium

Known as: PhMe2SiLi 
National Institutes of Health

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2 relations

Broader (2)

Organometallic CompoundsOrganosilicon Compounds

Papers overview

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2014
2014
Carboxylation with CO2 via Brook rearrangement: preparation of α-hydroxy acid derivatives.
In the presence of CsF, a wide range of α-substituted α-siloxy silanes were carboxylated under a CO2 atmosphere (1 atm) via Brook… 
2012
2012
Efficient synthesis of α-tertiary α-silylamines from aryl sulfonylimidates via one-pot, sequential C-Si/C-C bond formations.
An efficient and flexible route for the synthesis of α-tertiary (α,α-dibranched) α-silylamines via sequential reactions of… 
2004
2004
The extraordinary reactions of phenyldimethylsilyllithium with N,N-disubstituted amides.
Phenyldimethylsilyllithium reacts with N,N-dimethylamides in a variety of ways, depending upon the stoichiometry, the temperature… 
2003
2003
The reaction of phenyldimethylsilyllithium with N-phenylpyrrolidone.
Phenyldimethylsilyllithium reacts with N-phenylpyrrolidone 5 to give the known tetracyclic amines [2,3,3a,3b,4,5,6,11b-octahydro… 
2003
2003
Further reactions of phenyldimethylsilyllithium with N,N-dimethylamides.
Phenyldimethylsilyllithium reacts with several N,N-dimethylamides, and the intermediates, formulated here as successively a… 
2003
2003
Reactions of phenyldimethylsilyllithium with beta-N,N-dimethylaminoenones.
Phenyldimethylsilyllithium reacts with the beta-N,N-dimethylaminoenones 1 and 7, with the enal 5, and with ethyl beta-N,N… 
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