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methyl(trifluoromethyl)dioxirane

Known as: M(TFM)DO 
National Institutes of Health

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2 relations

Broader (1)

Ethylene Oxide
analogs & derivatives

Papers overview

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2017
2017
Electrosynthesis: A New Frontier in Aerobic Oxidation?
Baran and co-workers introduce a sustainable and scalable oxidation protocol for unactivated C–H bonds. 
2010
2010
Concerning selectivity in the oxidation of peptides by dioxiranes. Further insight into the effect of carbamate protecting groups.
With use of methyl(trifluoromethyl)dioxirane (TFDO), the oxidation of some tripeptide esters protected at the N-terminus with… 
2008
2008
Concerning the reactivity of dioxiranes. Observations from experiments and theory.
The challenging hypothesis of a "biphilic" (i.e., electrophilic vs nucleophilic) character for dioxirane reactivity, which… 
2007
2007
Oxidation of peptides by methyl(trifluoromethyl)dioxirane: the protecting group matters.
Representative Boc-protected and acetyl-protected peptide methyl esters bearing alkyl side chains undergo effective oxidation… 
2005
2005
Oxygenation of alkane C-H bonds with methyl(trifluoromethyl)dioxirane: effect of the substituents and the solvent on the reaction rate.
[Chemical reaction: See text] The mechanism of the oxygenation of alkane C-H bonds with methyl(trifluoromethyl)dioxirane (1a) is… 
2004
2004
Mechanism of the oxidation of sulfides by dioxiranes: conformational mobility and transannular interaction in the oxidation of thianthrene 5-oxide.
The detailed study of the oxidation of thianthrene 5-oxide (1) with methyl(trifluoromethyl)dioxirane (5b) in different solvents… 
2002
2002
Effect of geminal substitution on the strain energy of dioxiranes. Origin of the low ring strain of dimethyldioxirane.
The strain energies (SE) for dioxirane (DO) dimethyldioxirane (DMDO) and related dioxiranes have been examined by several methods… 
2001
2001
Influence of remote substituents on the equatorial/axial selectivity in the monooxygenation of methylene C--H bonds of substituted cyclohexanes.
The reactivity of individual C--H bonds in the methyl(trifluoromethyl)dioxirane TFDO oxygenation of stereogenic methylene groups… 
2001
2001
Oxyfunctionalization of non-natural targets by dioxiranes. 4. Efficient oxidation of Binor S using methyl(trifluoromethyl)dioxirane.
1997
1997
Organo Sulfonic Peracids. 4.(1) The Reaction of Arenesulfonylimidazoles with H(2)O(2) in the Presence of Ketones. A New Entry to Dioxiranes.
The reaction of ketones (acetone, 1,1,1-trifluoropropan-2-one) with the oxidation system (arenesulfonyl)imidazole (2)/H(2)O(2… 
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