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lucentamycin A

National Institutes of Health

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Oligopeptides

Papers overview

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2012
2012
Total synthesis and structural revision of lucentamycin A.
Lucentamycin A is a marine-derived peptide natural product harboring a unique 4-ethylidene-3-methylproline (Emp) subunit. The… 
2012
2012
Rhodium-catalyzed reductive cyclization of 1,6-enynes and stereoselective synthesis of the putative structure of lucentamycin A and its stereoisomers
2011
2011
An ester enolate-Claisen rearrangement route to substituted 4-alkylideneprolines. studies toward a definitive structural revision of lucentamycin A.
Substituted 4-alkylideneprolines represent a rare class of naturally occurring amino acids with promising biological activities… 
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