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[reaction: see text] Quantum mechanical calculations demonstrate that the second step of a Claisen-Diels-Alder reaction cascade… Expand The total synthesis of 1-O-methyllateriflorone (2) is described. The construction of the cage-like domain of the molecule… Expand Abstract A total synthesis of atroviridin ( 1 ) based on biosynthetic principles is presented. The tetracyclic xanthone structure… Expand An efficient synthetic approach to the tricyclic core 8 of lateriflorone is described. Essential to the synthesis was the… Expand A convergent strategy toward the synthesis of lateriflorone ( 5 ) is described. Our approach is based on biosynthetic… Expand