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hopanol

National Institutes of Health

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Triterpenes

Papers overview

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2019
2019
Enzymatic syntheses of novel carbocyclic scaffolds with a 6,5 + 5,5 ring system by squalene-hopene cyclase.
Squalene-hopene cyclase (SHC) converts acyclic squalene 1 into the 6,6,6,6,5-fused pentacyclic triterpenes hopene and hopanol… 
2018
2018
Alicyclobacillus acidocaldarius Squalene‐Hopene Cyclase: The Critical Role of Steric Bulk at Ala306 and the First Enzymatic Synthesis of Epoxydammarane from 2,3‐Oxidosqualene
The acyclic molecule squalene (1) is cyclized into 6,6,6,6,5‐fused pentacyclic hopene (2) and hopanol (3; ca. 5:1) through the… 
2018
2018
Mutated variants of squalene-hopene cyclase: enzymatic syntheses of triterpenes bearing oxygen-bridged monocycles and a new 6,6,6,6,6-fusded pentacyclic scaffold, named neogammacerane, from 2,3…
Squalene-hopene cyclase (SHC) catalyzes the conversion of acyclic squalene molecule into a 6,6,6,6,5-fused pentacyclic hopene and… 
2018
2018
Squalene-Hopene Cyclase: Mechanistic Insights into the Polycyclization Cascades of Squalene Analogs Bearing Ethyl and Hydroxymethyl Groups at the C-2 and C-23 Positions.
Squalene-hopene cyclase (SHC) catalyzes the conversion of squalene 1 into 6,6,6,6,5-fused pentacyclic hopene 2 and hopanol 3. To… 
2008
2008
Anhydrobacteriohopanetetrol in Deep Subsurface Sediments From Nankai Trough and Gulf of Mexico
Anhydrobacteriohopanetetrol (anhydroBHT) is the most abundant hopanol in sediments from ODP Leg 190, Nankai Trough and IODP Exp… 
2008
2008
(Figure 3) TOC-content, lipid biomarkers, dinosterol, and hopanol of Namibian sediments
2004
2004
Influence of ethanol on the hopanoid content and the fatty acid pattern in batch and continuous cultures of Zymomonas mobilis
By thin layer chromatographic, gas-liquid chromatographic, and mass spectrometric methods 1,2,3,4-tetrahydroxypentane-29-hopane… 
2004
2004
Site-directed Mutagenesis Experiments on the Putative Deprotonation Site of Squalene-hopene Cyclase from Alicyclobacillus acidocaldarius Tsutomu
To provide insight into the catalytic mechanism for the final deprotonation reaction of squalene-hopene cyclase (SHC) from… 
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