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galactal, (D)-isomer

Known as: d-galactal 
National Institutes of Health

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galactal

Papers overview

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2019
2019
Perfluorophenylboronic acid-catalyzed direct α-stereoselective synthesis of 2-deoxygalactosides from deactivated peracetylated d-galactal.
Perfluorophenylboronic acid 1c catalyzes the direct stereoselective addition of alcohol nucleophiles to deactivated peracetylated… Expand
2018
2018
Palladium catalyzed stereocontrolled synthesis of C-aryl glycosides using glycals and arenediazonium salts at room temperature.
A stereocontrolled synthesis of aryl-C-glycosides was achieved using glycals and aryldiazonium salts in the presence of palladium… Expand
2018
2018
Glycal Metallanitrenes for 2-Amino Sugar Synthesis: Amidoglycosylation of Gulal-, Allal-, Glucal-, and Galactal 3-Carbamates.
The rhodium(II)-catalyzed oxidative cyclization of glycal 3-carbamates with in situ incorporation of an alcohol nucleophile at… Expand
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2016
2016
Benzylation Reactions in DMF Lead to an Impurity Which Acts as an Organocatalyst Poison in Thiourea-Catalyzed Glycosylations.
The benzylation of alcohols with the commonly used combination of benzyl bromide and sodium hydride in DMF can lead to the… Expand
2014
2014
Elucidating the relationship between substrate and inhibitor binding to the active sites of tetrameric β-galactosidase
The activities of hundreds of single molecules of β-galactosidase were monitored in the presence of fluorogenic substrates and… Expand
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2012
2012
Measurement of the activity of individual subunits of single molecules of the tetrameric enzyme β-galactosidase.
Escherichia coli β-galactosidase was incubated in the presence of the slow-release inhibitor D-galactal for 30 min at a… Expand
2007
2007
Palladium-Catalyzed Stereoselective Formation of α-O-Glycosides.
A novel method for palladium-catalyzed stereoselective formation of r-O-glycosides has been developed. This strategy relies on… Expand
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2000
2000
Synthesis of the C-glycoside analogue of a novel sialyl Lewis X mimetic.
Sialyl Lewis X (sLex) mimetics that can function as selectin antagonists have received considerable attention in connection with… Expand
1986
1986
Reversion reactions of beta-galactosidase (Escherichia coli).
The reversion reactions of beta-galactosidase (Escherichia coli) produced beta-galactosyl-galactoses and beta-galactosyl-glucoses… Expand
1979
1979
The ineffectiveness of analogs of D-galactal as competitive inhibitors of, and substrates for, beta-D-galactosidase from Escherichia coli.
2,6-Anhydro-3-deoxy-aldehydo-D-lyxo-hept-2-enose (7) and 2,6-anhydro-3-deoxy-D-lyxo-hept-2-enitol (8) were synthesized as half… Expand
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