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galactal, (D)-isomer

Known as: d-galactal 
 
National Institutes of Health

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galactal

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2019
2019
Perfluorophenylboronic acid-catalyzed direct α-stereoselective synthesis of 2-deoxygalactosides from deactivated peracetylated d-galactal.
Perfluorophenylboronic acid 1c catalyzes the direct stereoselective addition of alcohol nucleophiles to deactivated peracetylated… Expand
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2018
2018
Palladium catalyzed stereocontrolled synthesis of C-aryl glycosides using glycals and arenediazonium salts at room temperature.
A stereocontrolled synthesis of aryl-C-glycosides was achieved using glycals and aryldiazonium salts in the presence of palladium… Expand
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2018
2018
Glycal Metallanitrenes for 2-Amino Sugar Synthesis: Amidoglycosylation of Gulal-, Allal-, Glucal-, and Galactal 3-Carbamates.
The rhodium(II)-catalyzed oxidative cyclization of glycal 3-carbamates with in situ incorporation of an alcohol nucleophile at… Expand
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2016
2016
Benzylation Reactions in DMF Lead to an Impurity Which Acts as an Organocatalyst Poison in Thiourea-Catalyzed Glycosylations.
The benzylation of alcohols with the commonly used combination of benzyl bromide and sodium hydride in DMF can lead to the… Expand
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2014
2014
Elucidating the relationship between substrate and inhibitor binding to the active sites of tetrameric β-galactosidase
The activities of hundreds of single molecules of β-galactosidase were monitored in the presence of fluorogenic substrates and… Expand
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2012
2012
Measurement of the activity of individual subunits of single molecules of the tetrameric enzyme β-galactosidase.
Escherichia coli β-galactosidase was incubated in the presence of the slow-release inhibitor D-galactal for 30 min at a… Expand
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2007
2007
Palladium-Catalyzed Stereoselective Formation of α-O-Glycosides.
A novel method for palladium-catalyzed stereoselective formation of r-O-glycosides has been developed. This strategy relies on… Expand
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2000
2000
Synthesis of the C-glycoside analogue of a novel sialyl Lewis X mimetic.
Sialyl Lewis X (sLex) mimetics that can function as selectin antagonists have received considerable attention in connection with… Expand
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1986
1986
Reversion reactions of beta-galactosidase (Escherichia coli).
The reversion reactions of beta-galactosidase (Escherichia coli) produced beta-galactosyl-galactoses and beta-galactosyl-glucoses… Expand
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1979
1979
The ineffectiveness of analogs of D-galactal as competitive inhibitors of, and substrates for, beta-D-galactosidase from Escherichia coli.
2,6-Anhydro-3-deoxy-aldehydo-D-lyxo-hept-2-enose (7) and 2,6-anhydro-3-deoxy-D-lyxo-hept-2-enitol (8) were synthesized as half… Expand
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