fulvene
National Institutes of Health
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The last missing example of the four archetypical cycloaromatizations of enediynes and enynes was discovered by combining a…
The synthesis, structural, and electronic properties of nine 1,3-diphenyl-6-alkyl/aryl substituted pentafulvenes were studied…
A new approach to functionalized fulvenes with an enone or enal moiety has been developed through gold-catalyzed intramolecular…
Fulvene is a non-aromatic molecule, but variation of the electron-donating/withdrawing power of substituents exo to the five…
The mechanism of the photochemical C(2)-C(6) cyclization of enyne-allenes has been studied through radical clock, intramolecular…
Constrained optimizations in the space of S1/S0 intersection are used to map the seam of degeneracy at which the singlet-excited…
A variety of polycyclic ring skeletons (e.g., kigelinol, neoamphilectane, and kempene systems) can be prepared rapidly via…
Fulvene derivatives, 20 mono- and 14 di-exocyclically substituted, were optimized at the B3LYP/6-311+G level of theory…