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fluorobis(phenylsulfonyl)methane

National Institutes of Health

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3 relations

Broader (2)

Hydrocarbons, FluorinatedMethane
analogs & derivatives

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2013
2013
DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones
A DIAD-mediated metal-free cross dehydrogenative coupling involving aliphatic tertiary amines and α-fluorinated sulfones leading… Expand
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2011
2011
Nucleophilic fluoromethylation of aldehydes with fluorobis(phenylsulfonyl)methane: the importance of strong Li-O coordination and fluorine substitution for C-C bond formation.
Recently, the selective introduction of fluorinated moieties into organic molecules with a-fluorinated carbanions has attracted… Expand
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Highly Cited
2011
Highly Cited
2011
Highly enantio- and diastereoselective synthesis of β-methyl-γ-monofluoromethyl-substituted alcohols.
Enanatiopure β-methyl-γ-monofluoromethyl alcohols were prepared from the allylic alkylation between fluorobis(phenylsulfonyl… Expand
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Highly Cited
2009
Highly Cited
2009
Catalytic enantioselective conjugate addition of fluorobis(phenylsulfonyl)methane to enals: synthesis of chiral monofluoromethyl compounds.
A new highly catalytic enantioselective Michael addition of fluorobis(phenylsulfonyl)methane to alpha,beta-unsaturated aldehydes… Expand
Highly Cited
2009
Highly Cited
2009
Iridium-catalyzed regio- and enantioselective allylic alkylation of fluorobis(phenylsulfonyl)methane.
Highly regio- and enantioselective allylic alkylation of fluorobis(phenylsulfonyl)methane (FBSM) has been realized by [Ir(COD)Cl… Expand
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Highly Cited
2009
Highly Cited
2009
Formal highly enantioselective organocatalytic addition of fluoromethyl anion to alpha,beta-unsaturated aldehydes.
Symmetric fluoromethylation made easy: a highly enantioselective fluoromethyl addition to ?,?-unsaturated aldehydes is described… Expand
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Highly Cited
2009
Highly Cited
2009
Efficient nucleophilic fluoromethylation and subsequent transformation of alkyl and benzyl halides using fluorobis(phenylsulfonyl)methane.
An efficient methodology for the nucleophilic fluoromethylation of alkyl and benzyl halides using alpha-fluoro-alpha… Expand
Highly Cited
2008
Highly Cited
2008
Nucleophilic fluoroalkylation of alpha,beta-enones, arynes, and activated alkynes with fluorinated sulfones: probing the hard/soft nature of fluorinated carbanions.
We have successfully accomplished the nucleophilic fluoroalkylation of alpha,beta-enones, arynes, and activated alkynes with… Expand
Highly Cited
2007
Highly Cited
2007
Cinchona alkaloid-catalyzed enantioselective monofluoromethylation reaction based on fluorobis(phenylsulfonyl)methane chemistry combined with a Mannich-type reaction.
A catalytic protocol for the unprecedented enantioselective monofluoromethylation of in situ generated prochiral imines using 1… Expand
Highly Cited
2006
Highly Cited
2006
Fluorobis(phenylsulfonyl)methane: a fluoromethide equivalent and palladium-catalyzed enantioselective allylic monofluoromethylation.
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