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divinyltetramethyldisiloxane

National Institutes of Health

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Siloxanes

Papers overview

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2019
2019
Cobalt-catalyzed (E)-Selective Cross-dimerization of Terminal Alkynes via a Mechanism Involving Co(0/II) Redox Cycles.
We developed cobalt-catalyzed highly ( E )-selective cross-dimerization of terminal alkynes with terminal silylacetylenes, tert… 
2018
2018
Highly selective hydrosilylation of olefins and acetylenes by platinum(0) complexes bearing bulky N-heterocyclic carbene ligands.
Platinum complexes bearing bulky N-heterocyclic carbene (NHC) ligands, i.e., [Pt(IPr*)(dvtms)] (where, IPr* = 1,3-bis{2,6-bis… 
2017
2017
A Straightforward Access to Stable, 16 Valence-electron Phosphine-Stabilized Fe0 Olefin Complexes and their Reactivity.
The use of the dialkene divinyltetramethyldisiloxane (dvtms) allows easy access to the reactive 16 valence-electron complexes… 
2016
2016
Investigation of the tracking and erosion resistance of cured liquid silicone rubber containing ureido-modified MQ silicone resin
Ureido-modified MQ silicone resin (DIPUPES-MQ) was prepared by the hydrolytic condensation of tetraethoxysilane (TEOS… 
2015
2015
Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η(4)-diene) platinum(0) complexes.
A series of water-soluble (NHC)Pt(0)(dvtms) and (NHC)Pt(0)(AE) complexes containing different sulfonated NHC ligands (dvtms… 
Highly Cited
2014
Highly Cited
2014
(Aminocarbene)(divinyltetramethyldisiloxane)iron(0) compounds: a class of low-coordinate iron(0) reagents.
The combined use of aminocarbene and divinyltetramethyldisiloxane (dvtms) as supporting ligands enables the access of… 
Highly Cited
2014
Highly Cited
2014
Three-coordinate cobalt(IV) and cobalt(V) imido complexes with N-heterocyclic carbene ligation: synthesis, structure, and their distinct reactivity in C-H bond amination.
The reaction of the cobalt(0) alkene complex [(IMes)Co(η(2):η(2)-dvtms)] (1) (IMes = 1,3-bis(1',3',5'-trimethylphenyl)imidazol-2… 
2010
2010
The role of the dielectric interface in organic transistors: a combined device and photoemission study
2009
2009
Palladium-catalyzed cyclopropanation of alkenyl silanes by diazoalkanes: evidence for a Pd(0) mechanism.
Alkenyl silanes are efficiently converted to the corresponding silyl cyclopropanes in the presence of a slight excess of… 
2006
2006
Photo-induced phenomena in organic field-effect phototransistors based on conjugated polymer/fullerene blends and organic dielectric
Photo-induced phenomena were investigated in photoresposive organic field-effect transistors (photOFETs) based on conjugated… 
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