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divinyltetramethyldisiloxane

 
National Institutes of Health

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Siloxanes

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2019
2019
Cobalt-catalyzed (E)-Selective Cross-dimerization of Terminal Alkynes via a Mechanism Involving Co(0/II) Redox Cycles.
We developed cobalt-catalyzed highly ( E )-selective cross-dimerization of terminal alkynes with terminal silylacetylenes, tert… Expand
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2019
2019
Synthesis of (E)-1,4-disilsesquioxylsubstituted but-1-en-3-ynes via platinum-catalyzed dimerization of ethynylsiloxysilsesquioxanes.
A new platinum complex bearing bulky N-heterocyclic carbene ligand of the general formula [Pt(IPr*Ph)(dvtms)] (where IPr*Ph = 1,3… Expand
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2018
2018
Highly selective hydrosilylation of olefins and acetylenes by platinum(0) complexes bearing bulky N-heterocyclic carbene ligands.
Platinum complexes bearing bulky N-heterocyclic carbene (NHC) ligands, i.e., [Pt(IPr*)(dvtms)] (where, IPr* = 1,3-bis{2,6-bis… Expand
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2017
2017
A Straightforward Access to Stable, 16 Valence-electron Phosphine-Stabilized Fe0 Olefin Complexes and their Reactivity.
The use of the dialkene divinyltetramethyldisiloxane (dvtms) allows easy access to the reactive 16 valence-electron complexes… Expand
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2016
2016
Investigation of the tracking and erosion resistance of cured liquid silicone rubber containing ureido-modified MQ silicone resin
Ureido-modified MQ silicone resin (DIPUPES-MQ) was prepared by the hydrolytic condensation of tetraethoxysilane (TEOS… Expand
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2015
2015
Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene (η(4)-diene) platinum(0) complexes.
A series of water-soluble (NHC)Pt(0)(dvtms) and (NHC)Pt(0)(AE) complexes containing different sulfonated NHC ligands (dvtms… Expand
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2014
2014
(Aminocarbene)(divinyltetramethyldisiloxane)iron(0) compounds: a class of low-coordinate iron(0) reagents.
The combined use of aminocarbene and divinyltetramethyldisiloxane (dvtms) as supporting ligands enables the access of… Expand
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2014
2014
Three-coordinate cobalt(IV) and cobalt(V) imido complexes with N-heterocyclic carbene ligation: synthesis, structure, and their distinct reactivity in C-H bond amination.
The reaction of the cobalt(0) alkene complex [(IMes)Co(η(2):η(2)-dvtms)] (1) (IMes = 1,3-bis(1',3',5'-trimethylphenyl)imidazol-2… Expand
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2010
2010
The role of the dielectric interface in organic transistors: A combined device and photoemission study
Abstract Here the device performance is shown to be directly related to the measured electronic level alignment at the dielectric… Expand
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2001
2001
Production method of platinum-alkenylpolysiloxane complexes, in particular platinum-divinyltetramethyldisiloxane
Preparation process for platinum-alkenylpolysiloxane complexes, in particular platinum-divinyltetramethyldisiloxane, by reaction… Expand
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