disilenyl silylene
National Institutes of Health
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The highly reactive silicon congeners of cyclopropene, cyclotrisilenes (c-Si3 R4 ), typically undergo either π-addition to the Si…
The rearrangements of (chlorosilyl)disilenes R2(Cl)Si-(Tip)Si=SiTip2 (5a,b: Tip = 2,4,6-iPr3C6H2, a: R = Me, b: R = Ph…
Tetrakis(di-tert-butylmethylsilyl)disilene (1) was treated with 2.2 equiv of metal naphthalenide (M = Li, Na) in THF. When a…
A summary of recent advances on the chemistry and photophysics of silylene-spaced divinylarene copolymers is presented. The…
Reduction of Cl2Si[(NR)2C6H4-1,2] (R = CH2Bu(t)) with potassium is known to lead to the stable silylene Si[(NR)2C6H4-1,2] (1…
which isprotected kinetically by the bulky helmet substituent1,1,4,4-tetrakis(trimethylsilyl)butane-1,4-diyl, does notdimerize to…
The geometry and bonding nature of Cp(CO)(2)W(CCH)(SiH(2)) (1) and the reaction leading to the formation of 1 from Cp(CO)(2)W(SiH…
An unusual product formation is observed for the insertion reaction of the thermally stable silylene Si[(NCH(2)Bu(t))(2)C(6)H(4…
The thermally stable silylene Si[(NCH(2)Bu(t))(2)C(6)H(4)-1,2] 1 undergoes oxidative addition reactions with the alkali metal…
Silicon squares up: The silylene Si[1,2-(NR)2C6H4] (R=CH2tBu) is thermally stable owing to its bulky substituent. What effect…