Skip to search formSkip to main contentSkip to account menu

disilenyl silylene

National Institutes of Health

Related topics

Related topics

1 relation

Broader (1)

Organosilicon Compounds

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2017
2017
Reactivity of an amidinato silylene and germylene toward germanium(ii), tin(ii) and lead(ii) halides.
The coordination chemistry of an amidinato silylene and germylene toward group 14 element(ii) halides is described. The reaction… 
2012
2012
Electronic and Steric Effects on the Lewis Acidities of Transient Silylenes and Germylenes: Equilibrium Constants for Complexation with Chalcogen and Pnictogen Donors
The Lewis acid–base complexation reactions of dimethyl-, diphenyl-, and dimesitylsilylene (SiMe2, SiPh2, and SiMes2, respectively… 
2009
2009
The gas-phase reaction between silylene and 2-butyne: kinetics, isotope studies, pressure dependence studies and quantum chemical calculations.
Time-resolved kinetic studies of the reactions of silylene, SiH(2), and dideutero-silylene, SiD(2), generated by laser flash… 
2008
2008
The addition reaction between silylene and ethyne: further isotope studies, pressure dependence studies, and quantum chemical calculations.
Time-resolved kinetic studies of the reaction of dideutero-silylene, SiD 2, generated by laser flash photolysis of phenylsilane-d… 
2006
2006
Alternating divinylarene-silylene copolymers.
A summary of recent advances on the chemistry and photophysics of silylene-spaced divinylarene copolymers is presented. The… 
2005
2005
Reactions of a stable silylene with halocarbons.
An unusual product formation is observed for the insertion reaction of the thermally stable silylene Si[(NCH(2)Bu(t))(2)C(6)H(4… 
2004
2004
Reaction of the silylene Si[(NCH2But)2C6H4-1,2] with the alkali metal silylamides M[N(SiMe3)R](M = Li, Na or K; R = SiMe3 or SiMe2Ph).
The thermally stable silylene Si[(NCH(2)Bu(t))(2)C(6)H(4)-1,2] 1 undergoes oxidative addition reactions with the alkali metal… 
2004
2004
An isolable radical anion and dianion of a cyclotetrasilane: synthesis and structure of [Si(1,2-(NEt)2C6H4)](4)(-)(.-) and [Si(1,2-(NEt)2C6H4)](4)(2-).
Silicon squares up: The silylene Si[1,2-(NR)2C6H4] (R=CH2tBu) is thermally stable owing to its bulky substituent. What effect… 
2003
2003
Electron deficient bridges involving silylenes: a theoretical study.
Ab initio and density functional studies show that silylenes can form complexes with BH(3) and the resultant complexes possess 3c… 
2002
2002
Silyl, hydrido-silylene, or other bonding modes: some unusual structures of [(dhpe)Pt(SiHR2)]+ (dhpe = H2P-CH2-CH2-PH2; R = H, Me, SiH3, Cl, OMe, NMe2) and [(dhpe)Pt(SiR3)](+) (R = Me, Cl) from DFT…
DFT (B3LYP) calculations have been carried out in order to quantitatively evaluate the energies and stereochemistry of the… 
By clicking accept or continuing to use the site, you agree to the terms outlined in our Privacy Policy (opens in a new tab), Terms of Service (opens in a new tab), and Dataset License (opens in a new tab)