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dimethylaluminum chloride

 
National Institutes of Health

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Organometallic Compounds

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2017
2017
Identification of Dimeric Methylalumina Surface Species during Atomic Layer Deposition Using Operando Surface-Enhanced Raman Spectroscopy.
Operando surface-enhanced Raman spectroscopy (SERS) was used to successfully identify hitherto unknown dimeric methylalumina… Expand
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2014
2014
Monomethylaluminum and dimethylaluminum pyrrolylaldiminates for the ring-opening polymerization of rac-lactide: effects of ligand structure and coordination geometry.
Two series of aluminum alkyl complexes supported by pyrrolylaldiminate ligands, LAlMe2 (1a-7a) and L2AlMe (1b-7b), were… Expand
2011
2011
[3+2] cycloaddition reaction of cyclopropyl ketones with alkynes catalyzed by nickel/dimethylaluminum chloride.
Transition-metal-catalyzed cycloaddition reactions have received increasing attention as straightforward methods for the… Expand
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Highly Cited
2008
Highly Cited
2008
Enantioselective synthesis of all-carbon quaternary stereogenic centers by catalytic asymmetric conjugate additions of alkyl and aryl aluminum reagents to five-, six-, and seven-membered-ring beta…
advances involving catalytic ACA reactions of alkyl metal (mostly dialkyl zinc) reagents, a number of critical shortcomings… Expand
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2008
2008
Early transition metal complexes bearing a C-capped tris(phenolate) ligand incorporating a pendant imine arm: synthesis, structure, and ethylene polymerization behavior.
The ligand 3-[2,2'-methylenebis(4,6-di- tert-butylphenol)-5- tert-butylsalicylidene-(2,6-diisopropyl)phenylimine] (L(1)H 3) was… Expand
2006
2006
Adsorption reactions of dimethylaluminum isopropoxide and water on the H/Si(100)-2 x 1 surface: initial reactions for atomic layer deposition of Al2O3.
The surface reaction pathways of dimethylaluminum isopropoxide (DMAI) and water with the H/Si(100)-2 x 1 surface were… Expand
2005
2005
Activation of metallocenes for olefin polymerization as monitored by IR spectroscopy.
Binary mixtures of Cp2ZrMe2, Cp2ZrCl2, dimethylaluminum chloride, trimethylaluminum, and methylaluminoxane (MAO), as well as… Expand
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2005
2005
Synthesis of N-Fmoc-(2S,3S,4R)-3,4-dimethylglutamine: An application of lanthanide-catalyzed transamidation.
N-Fmoc-(2S,3S,4R)-3,4-dimethylglutamine (6) was synthesized from tert-butyl N-Boc-(2S,3S,4R)-dimethylpyroglutamate (13). This… Expand
Highly Cited
2001
Highly Cited
2001
The exceptional chelating ability of dimethylaluminum chloride and methylaluminum dichloride. The merged stereochemical impact of alpha- and beta-stereocenters in chelate-controlled carbonyl addition…
A systematic investigation of the stereoselectivity in Lewis acid-promoted (Mukaiyama) aldol reactions of achiral unsubstituted… Expand
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1994
1994
Infrared Spectroscopy of Trimethylaluminum and Dimethylaluminum chloride adsorbed on Alumina
The species formed by adsorption of trimethylaluminum and dimethylaluminum chloride on y-alumina that has been dehydroxylated at… Expand
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