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diisopropylamine, lithium salt

Known as: lithium diisopropylamide 
National Institutes of Health

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diisopropylamine

Papers overview

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Highly Cited
2016
Highly Cited
2016
Medium-Ring Nitrogen Heterocycles through Migratory Ring Expansion of Metalated Ureas.
Simple benzo-fused nitrogen heterocycles (indolines, tetrahydroquinolines, and their homologues) undergo migratory ring expansion… 
Highly Cited
2013
Highly Cited
2013
Oxidative trifluoromethylation of unactivated olefins: an efficient and practical synthesis of α-trifluoromethyl-substituted ketones.
The incorporation of a CF3 group in a compound of pharmacological relevance usually results in significant enhancement of its… 
Highly Cited
2013
Highly Cited
2013
Synthetically important alkali-metal utility amides: lithium, sodium, and potassium hexamethyldisilazides, diisopropylamides, and tetramethylpiperidides.
Most synthetic chemists will have at some point utilized a sterically demanding secondary amide (R2 N(-) ). The three most… 
Highly Cited
2012
Highly Cited
2012
Synthesis and physicochemical properties of metallobacteriochlorins.
Access to metallobacteriochlorins is essential for investigation of a wide variety of fundamental photochemical processes, yet… 
2011
2011
Regioselective asymmetric α,α-bisalkylation of ketones via complex-induced syn-deprotonation of chiral N-amino cyclic carbamate hydrazones.
The first general method for the asymmetric α,α-bisalkylation of ketones having both α- and α'-protons is described. Both… 
Highly Cited
2011
Highly Cited
2011
Regioselective lithium diisopropylamide-mediated ortholithiation of 1-chloro-3-(trifluoromethyl)benzene: role of autocatalysis, lithium chloride catalysis, and reversibility.
Ortholithiation of 1-chloro-3-(trifluoromethyl)benzene with lithium diisopropylamide (LDA) in tetrahydrofuran at -78 °C displays… 
Highly Cited
2010
Highly Cited
2010
Efficient microwave-assisted synthesis of secondary alkylpropargylamines by using A3-coupling with primary aliphatic amines.
Multicomponent reactions (MCRs) have attracted much attention in the framework of combinatorial chemistry owing to their… 
Highly Cited
2009
Highly Cited
2009
Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 degrees C reveal substantial… 
2006
2006
Lithium diisopropylamide-mediated ortholithiation and anionic fries rearrangement of aryl carbamates: role of aggregates and mixed aggregates.
Structural and mechanistic studies of the lithium diisopropylamide (LDA)-mediated anionic Fries rearrangements of aryl carbamates… 
Highly Cited
2003
Highly Cited
2003
Regiospecific metalation of oligobromobenzenes.
The metalation of selected oligobromobenzenes with lithium diisopropylamide (LDA) was investigated. 1,3-Dibromo-substituted… 
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