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diisopropylamine, lithium salt

Known as: lithium diisopropylamide 
National Institutes of Health

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diisopropylamine

Papers overview

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Highly Cited
2013
Highly Cited
2013
Oxidative trifluoromethylation of unactivated olefins: an efficient and practical synthesis of α-trifluoromethyl-substituted ketones.
The incorporation of a CF3 group in a compound of pharmacological relevance usually results in significant enhancement of its… 
Highly Cited
2012
Highly Cited
2012
Synthesis and physicochemical properties of metallobacteriochlorins.
Access to metallobacteriochlorins is essential for investigation of a wide variety of fundamental photochemical processes, yet… 
2011
2011
Regioselective asymmetric α,α-bisalkylation of ketones via complex-induced syn-deprotonation of chiral N-amino cyclic carbamate hydrazones.
The first general method for the asymmetric α,α-bisalkylation of ketones having both α- and α'-protons is described. Both… 
Highly Cited
2011
Highly Cited
2011
Regioselective lithium diisopropylamide-mediated ortholithiation of 1-chloro-3-(trifluoromethyl)benzene: role of autocatalysis, lithium chloride catalysis, and reversibility.
Ortholithiation of 1-chloro-3-(trifluoromethyl)benzene with lithium diisopropylamide (LDA) in tetrahydrofuran at -78 °C displays… 
Highly Cited
2010
Highly Cited
2010
1,4-addition of lithium diisopropylamide to unsaturated esters: role of rate-limiting deaggregation, autocatalysis, lithium chloride catalysis, and other mixed aggregation effects.
Lithium diisopropylamide (LDA) in tetrahydrofuran at -78 °C undergoes 1,4-addition to an unsaturated ester via a rate-limiting… 
Highly Cited
2010
Highly Cited
2010
Efficient microwave-assisted synthesis of secondary alkylpropargylamines by using A3-coupling with primary aliphatic amines.
Multicomponent reactions (MCRs) have attracted much attention in the framework of combinatorial chemistry owing to their… 
Highly Cited
2009
Highly Cited
2009
Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis.
Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 degrees C reveal substantial… 
2006
2006
Lithium diisopropylamide-mediated ortholithiation and anionic fries rearrangement of aryl carbamates: role of aggregates and mixed aggregates.
Structural and mechanistic studies of the lithium diisopropylamide (LDA)-mediated anionic Fries rearrangements of aryl carbamates… 
Highly Cited
2003
Highly Cited
2003
Regiospecific metalation of oligobromobenzenes.
The metalation of selected oligobromobenzenes with lithium diisopropylamide (LDA) was investigated. 1,3-Dibromo-substituted… 
1989
1989
Structure and reactivity of lithium diisopropylamide (LDA). The consequences of aggregation and solvation during the metalation of an N,N-dimethylhydrazone
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