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dicarbonyldiphenylaminedithiocarbamate rhodium(I)

Known as: Rh(CO)2(DPA-dtc) 
 
National Institutes of Health

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2 relations

Broader (2)

Organometallic CompoundsThiocarbamates

Papers overview

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2012
2012
Ultrafast continuum mid-infrared spectroscopy: probing the entire vibrational spectrum in a single laser shot with femtosecond time resolution.
Until now, ultrafast IR spectroscopy has been limited by the bandwidth of optical parametric amplifiers, typically 100-400  cm(-1… Expand
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2011
2011
Relationship between electrochemical potentials and substitution reaction rates of ferrocene-containing β-diketonato rhodium(I) complexes; cytotoxicity of [Rh(FcCOCHCOPh)(cod)].
A series of ferrocene-containing rhodium complexes of the type [Rh(FcCOCHCOR)(cod)] (cod = 1,5-cyclooctadiene) with R = CF(3), 1… Expand
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Highly Cited
2010
Highly Cited
2010
Steric vs. electronic anomaly observed from iodomethane oxidative addition to tertiary phosphine modified rhodium(i) acetylacetonato complexes following progressive phenyl replacement by cyclohexyl…
Rhodium(i) acetylacetonato complexes of the formula [Rh(acac)(CO)(PR(3))] [acac = acetylacetonate, PR(3) = PPh(3) 1, PCyPh(2) 2… Expand
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2009
2009
Steric tuning of the amidomonophosphane-rhodium(I) catalyst in asymmetric addition of arylboroxines to N-phosphinoyl aldimines.
Highly enantioselective rhodium-catalyzed addition of arylboroxines to N-phosphinoylaldimines was realized by the steric tuning… Expand
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2009
2009
Synthesis and structure of indenyl rhodium(I) complexes containing unsaturated phosphines: catalyst precursors for alkene hydroboration.
The indenyl compound (eta(5)-C(9)H(7))Rh(coe)(2) (1, coe = cis-cyclooctene) has been prepared as a thermally stable alternative… Expand
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2009
2009
A homogeneous, recyclable rhodium(I) catalyst for the hydroarylation of Michael acceptors.
A robust and practical polymer-supported, recyclable biphephos rhodium(I) catalyst has been developed. Control of polymer… Expand
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2007
2007
Addition of alkynes to aldehydes and activated ketones catalyzed by rhodium-phosphine complexes.
A mixture of 2-(di-tert-butylphosphino)biphenyl and dicarbonylacetonato rhodium(I) provides an effective catalyst system for the… Expand
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Highly Cited
2004
Highly Cited
2004
N-Boc-L-valine-connected amidomonophosphane rhodium(I) catalyst for asymmetric arylation of N-tosylarylimines with arylboroxines.
A catalytic asymmetric arylation of sterically tuned imines with arylboroxines was developed by using N-Boc-l-valine-connected… Expand
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2003
2003
Zwitterionic relatives to the classic [(P-P)Rh(solv)2]+ ions: neutral catalysts active for H-E bond additions to olefins (E=C, Si, B).
Formally zwitterionic bis(phosphanyl)- and bis(amino)borate rhodium(I) complexes (see picture) can catalytically mediate the… Expand
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2002
2002
Hemilabile amidomonophosphine ligand-rhodium(I) complex-catalyzed asymmetric 1,4-addition of arylboronic acids to cycloalkenones.
The asymmetric 1,4-addition reaction of arylboronic acids with cycloalkenones was catalyzed by 1 mol % of an amidomonophosphine… Expand
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