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dicarbonyldiphenylaminedithiocarbamate rhodium(I)

Known as: Rh(CO)2(DPA-dtc) 
National Institutes of Health

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2 relations

Broader (2)

Organometallic CompoundsThiocarbamates

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2016
2016
Synthesis of a rhodium(i) germyl complex: a useful tool for C-H and C-F bond activation reactions.
The dihydrido germyl complex cis,fac-[Rh(GePh3)(H)2(PEt3)3] (2) was synthesized by an oxidative addition of HGePh3 at [Rh(H)(PEt3… 
2016
2016
Synthesis and reactions of C-phosphanylated thiazol-2-thiones.
The facile regioselective synthesis of the P(iii) substituted thiazol-2-thione 2 is presented. Reaction of 2 with… 
2016
2016
Rhodium(i), rhodium(iii) and iridium(iii) carbaporphyrins.
Treatment of a benzocarbaporphyrin with [Rh(CO)2Cl]2 in refluxing dichloromethane gave a rhodium(i) dicarbonyl complex, and… 
2015
2015
Isocyanate deinsertion from κ(1)-O amidates: facile access to perfluoroaryl rhodium(I) complexes.
Reaction of the amidate ligand salt, Na[N(Dipp)C(O)C6F5] () (Dipp = 2,6-diisopropylphenyl) with [Rh(NBD)Cl]2 (NBD = norbornadiene… 
2011
2011
Development of homogeneous and heterogenized rhodium(I) and palladium(II) complexes with ligands based on a chiral proton sponge building block and their application as catalysts.
Chiral compounds prepared from proton sponge building block 8-((2R,5R)-2,5-dimethylpyrrolidin-1-yl)naphthalen-1-amine were found… 
2009
2009
Synthesis and structure of indenyl rhodium(I) complexes containing unsaturated phosphines: catalyst precursors for alkene hydroboration.
The indenyl compound (eta(5)-C(9)H(7))Rh(coe)(2) (1, coe = cis-cyclooctene) has been prepared as a thermally stable alternative… 
2007
2007
Addition of alkynes to aldehydes and activated ketones catalyzed by rhodium-phosphine complexes.
A mixture of 2-(di-tert-butylphosphino)biphenyl and dicarbonylacetonato rhodium(I) provides an effective catalyst system for the… 
Highly Cited
2005
Highly Cited
2005
Cyclodiphosphazanes with hemilabile ponytails: synthesis, transition metal chemistry (Ru(II), Rh(I), Pd(II), Pt(II)), and crystal and molecular structures of mononuclear (Pd(II), Rh(I)) and bi- and…
Cyclodiphosphazanes having hemilabile ponytails such as cis-[(t)()BuNP(OC(6)H(4)OMe-o)](2) (2), cis-[(t)()BuNP(OCH(2)CH(2)OMe)](2… 
Highly Cited
2003
Highly Cited
2003
Zwitterionic relatives to the classic [(P-P)Rh(solv)2]+ ions: neutral catalysts active for H-E bond additions to olefins (E=C, Si, B).
Formally zwitterionic bis(phosphanyl)- and bis(amino)borate rhodium(I) complexes (see picture) can catalytically mediate the… 
2001
2001
Synthesis and reactivity of fluoro complexes. Part 1. Cyclooctadiene rhodium(I) complexes.
The synthesis of [RhF(COD)]n and its triphenylphosphine adduct 2, and a preliminary study of the reactivity of 2 are reported… 
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