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The highly reactive silicon congeners of cyclopropene, cyclotrisilenes (c-Si3 R4 ), typically undergo either π-addition to the Si… Expand 1,2,3-Trisilacyclopentadienes are obtained from the reactions of cyclotrisilene c-Si3R4 (R = iPr3C6H2) with phenyl and diphenyl… Expand The reactivity of the 2-phosphaethynolate anion (PCO−) towards a cyclic trisilene (cSi3(Tip)4) is reported. The result is the net… Expand In the presence of a Lewis acid or base, cyclotrisilene cSi3Tip4 (Tip = 2,4,6-triisopropylphenyl) reacts with CO to form stable… Expand In organic chemistry, compounds with adjacent alkene and carbene functionalities (vinyl carbenes) are studied widely as fleeting… Expand Carbon monoxide (CO) is a common ligand in transitionmetal chemistry. In organic chemistry, it is frequently used to introduce a… Expand The Cp*Si(+) cation acts as a stoichiometric source of silicon in the reaction with the disilenide Tip(2)Si=Si(Tip)Li (Tip = 2,4… Expand A novel stable tetrasila-1,3-diene 3 was synthesized by the reduction with sodium of the corresponding 1,2,2-tribromodisilane. X… Expand Cyclotrisilene、cyclotrigermene and related molecules were calculated by several methods of quantum chemistry in Gaussian-98… Expand Red-orange crystals of cyclotrisilene 3 were obtained by the reaction of the dibromotrisilane 1 and the tribromodisilane 2 with… Expand