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copper-bispidine

National Institutes of Health

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Organometallic Compounds

Papers overview

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2016
2016
A Bispidine Iron(IV)-Oxo Complex in the Entatic State.
For a series of Fe(IV) =O complexes with tetra- and pentadentate bispidine ligands, the correlation of their redox potentials… 
Highly Cited
2016
Highly Cited
2016
Deformylation Reaction by a Nonheme Manganese(III)-Peroxo Complex via Initial Hydrogen-Atom Abstraction.
Metal-peroxo intermediates are key species in the catalytic cycles of nonheme metalloenzymes, but their chemical properties and… 
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2013
2013
Optimization of pentadentate bispidines as bifunctional chelators for 64Cu positron emission tomography (PET).
Pentadentate bispidine ligands (3,7-diazabicyclo[3.3.1]nonanes) are optimized for maximum complex stability and facile… 
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Highly Cited
2009
Highly Cited
2009
Oxidation of cyclohexane by high-valent iron bispidine complexes: tetradentate versus pentadentate ligands.
The iron-bispidine-catalyzed oxidation of cyclohexane with H(2)O(2), where either a tetradentate or a pentadentate bispidine… 
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2009
2009
Synthesis, structure, and highly efficient copper-catalyzed aziridination with a tetraaza-bispidine ligand.
The distorted trigonal-bipyramidal Cu(II) complex [Cu(L(1))(NCCH(3))](2+) of the novel tetradentate bispidine-derived ligand L(1… 
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Highly Cited
2009
Highly Cited
2009
Hexadentate bispidine derivatives as versatile bifunctional chelate agents for copper(II) radioisotopes.
The preparation and use of bispidine derivatives (3,7-diazabicyclo[3.3.1]nonane) as chelate ligands for radioactive copper… 
Highly Cited
2007
Highly Cited
2007
A density functional theory study of the reaction of the biomimetic iron(II) complex of a tetradentate bispidine ligand with H2O2.
Three pathways for the reaction of bispidine-iron(II) complexes (where bispidine is a rigid tetradentate amine/pyridine ligand… 
2006
2006
Catecholase activity of dicopper(II)-bispidine complexes: stabilities and structures of intermediates, kinetics and reaction mechanism
A mechanism for the oxidation of 3,5-di-tert-butylcatechol (dtbc) with dioxygen to the corresponding quinone (dtbq), catalyzed by… 
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2006
2006
Spin-crossover in an iron(III)-bispidine-alkylperoxide system.
The iron(II) complex of a tetradentate bispidine ligand with two tertiary amines and two pyridine groups (L = dimethyl [3,7… 
Highly Cited
2005
Highly Cited
2005
Coordination chemistry of a new rigid, hexadentate bispidine-based bis(amine)tetrakis(pyridine) ligand.
The hexadentate bispidine-based ligand 2,4-bis(2-pyridyl)-3,7-bis(2-methylenepyridine)-3,7-diazabicyclo[3.3.1]nonane-9-on-1,5-bis… 
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