copper-bispidine

 
National Institutes of Health

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Organometallic Compounds

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2016
2016
Deformylation Reaction by a Nonheme Manganese(III)-Peroxo Complex via Initial Hydrogen-Atom Abstraction.
Metal-peroxo intermediates are key species in the catalytic cycles of nonheme metalloenzymes, but their chemical properties and… (More)
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2015
2015
Cu(II)-selective bispidine-dye conjugates.
The substitution of tetradentate bispidine ligands with rhodamine and cyanine dye molecules, coupled to an amine donor, forming… (More)
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2015
2015
The First Modular Route to Core-Chiral Bispidine Ligands and Their Application in Enantioselective Copper(II)-Catalyzed Henry Reactions.
The first modular and flexible synthesis of core-chiral bispidines was achieved by using an "inside-out" strategy. The key… (More)
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2014
2014
Bispidine dioxotetraaza macrocycles: a new class of bispidines for (64)Cu PET imaging.
The three new dioxo-tetraazamacrocyclic ligands with a fused, very rigid bispidine (3,7-diazabicyclo[3.3.1]nonane) group… (More)
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2013
2013
The 3,7-diazabicyclo[3.3.1]nonane scaffold for subtype selective nicotinic acetylcholine receptor ligands. Part 2: carboxamide derivatives with different spacer motifs.
3,7-Diazabicyclo[3.3.1]nonane (bispidine) based nicotinic acetylcholine receptor (nAChR) ligands have been synthesized and… (More)
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2013
2013
Optimization of pentadentate bispidines as bifunctional chelators for 64Cu positron emission tomography (PET).
Pentadentate bispidine ligands (3,7-diazabicyclo[3.3.1]nonanes) are optimized for maximum complex stability and facile… (More)
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2010
2010
The Ru(IV)=O-catalyzed sulfoxidation: a gated mechanism where O to S linkage isomerization switches between different efficiencies.
Two Ru(IV)=O catalysts with either a pentadentate bispidine ligand L(1) or a bidentate pyrazolate L(2)/terpy L(3) combination of… (More)
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2009
2009
Oxidation of cyclohexane by high-valent iron bispidine complexes: tetradentate versus pentadentate ligands.
The iron-bispidine-catalyzed oxidation of cyclohexane with H(2)O(2), where either a tetradentate or a pentadentate bispidine… (More)
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2009
2009
Synthesis, structure, and highly efficient copper-catalyzed aziridination with a tetraaza-bispidine ligand.
The distorted trigonal-bipyramidal Cu(II) complex [Cu(L(1))(NCCH(3))](2+) of the novel tetradentate bispidine-derived ligand L(1… (More)
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2008
2008
Stable five- and six-coordinate cobalt(III) complexes with a pentadentate bispidine ligand.
Cobalt(III) complexes are classics in coordination chemistry, and pentaamine as well as hexaamine Co complexes generally have a… (More)
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