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chiral amino acid racemization

The formation of a mixture of the two possible enantiomers from the D- or L-enantiomer of a chiral amino acid. [GOC:jsg, ISBN:0198506732]
National Institutes of Health

Papers overview

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2016
2016
Iminophenyl Oxazolinylphenylamine for Enantioselective Cobalt-Catalyzed Hydrosilylation of Aryl Ketones.
A new family of chiral iminophenyl oxazolinylphenylamines (IPOPA) was designed and synthesized through three steps from… 
Highly Cited
2013
Highly Cited
2013
Electrophilic rearrangements of chiral amides: a traceless asymmetric α-allylation.
A one-pot protocol for the asymmetric α-allylation reaction is reported relying on a key efficient asymmetric Claisen… 
Highly Cited
2013
Highly Cited
2013
Asymmetric electrophilic fluorocyclization with carbon nucleophiles.
Asymmetric Electrophilic Fluorocyclization with Carbon Nucleophiles Twist of ‘F’ate : Various helical-shaped fluorinated… 
2012
2012
Simple and efficient methods for discrimination of chiral diacids and chiral alpha-methyl amines.
The three-component chiral derivatization protocols have been developed for (1)H, (13)C and (19)F NMR spectroscopic… 
Highly Cited
2011
Highly Cited
2011
Chiral sulfonimide as a Brønsted acid organocatalyst for asymmetric Friedel-Crafts alkylation of indoles with imines.
Binaphthyl-based chiral sulfonimide (CSI) is demonstrated for the first time to be an efficient, strong Brønsted acid in… 
2008
2008
Model of CE enantioseparation systems with a mixture of chiral selectors. Part I. Theory of migration and interconversion.
2004
2004
Chiral metallacyclophanes: self-assembly, characterization, and application in asymmetric catalysis.
[structure: see text] A family of chiral metallacyclophanes has been readily assembled based on robust Pt-acetylide linkage and… 
Highly Cited
2002
Highly Cited
2002
Air-stable catalysts for highly efficient and enantioselective hydrogenation of aromatic ketones.
A series of chiral trans-[RuCl(2)(dipyridylphosphine)(1,2-diamine)] complexes have been synthesized and characterized by NMR and… 
2000
2000
First asymmetric hetero Diels-Alder reaction of 1-sulfinyl dienes with nitroso derivatives. A new entry to the synthesis of optically pure 1,4-imino-L-ribitol derivatives.
Hetero Diels-Alder (HDA) cycloaddition of chiral 1-p-tolylsulfinyl-1,3-pentadiene with benzyl nitrosoformate, under mild… 
1988
1988
A Synchrotron X-ray Study of a Solid-Solid Phase Transition in a Two-Dimensional Crystal
A measurement and interpretation on a molecular level of a phase transition in an ordered Langmuir monolayer is reported. The… 
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