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catalysis of free radical formation

Known as: catalysis of free radical generation, catalysis of free-radical biosynthesis, catalysis of free-radical generation 
Catalysis of a reaction that generates a free radical, a highly reactive molecule with an unsatisfied electron valence pair. [GOC:jl]
National Institutes of Health

Topic mentions per year

Topic mentions per year

1998-2016
01219982016

Papers overview

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2017
2017
Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis.
Donor-substituted diazo reagents, generated in situ from sulfonyl hydrazones in the presence of base, can serve as suitable… (More)
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2017
2017
Aquivion Perfluorosulfonic Superacid as an Efficient Pickering Interfacial Catalyst for the Hydrolysis of Triglycerides.
Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions… (More)
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2016
2016
Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides by Cobalt(II)-Based Metalloradical Catalysis: Effective Construction of Strained Heterobicyclic Structures.
Cobalt(II)-based metalloradical catalysis (MRC) has been successfully applied for effective construction of the highly strained 2… (More)
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2016
2016
Intramolecular 1,5-C(sp3)-H Radical Amination via Co(II)-Based Metalloradical Catalysis for Five-Membered Cyclic Sulfamides.
Co(II)-based metalloradical catalysis (MRC) proves effective for intramolecular 1,5-C-H amination of sulfamoyl azides under… (More)
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2014
2014
Direct sp(3)C-H acroleination of N-aryl-tetrahydroisoquinolines by merging photoredox catalysis with nucleophilic catalysis.
Sequence catalysis merging photoredox catalysis (PC) and nucleophilic catalysis (NC) has been realized for the direct sp(3) C-H… (More)
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2013
2013
Phosphinoalkylnitrile: Synthese und Koordinationsverhalten an Palladiumzentren Phosphinoalkylnitnles: Synthesis and Coordination Behaviour at Palladium Centres
Phosphinoalkylnitriles, Phosphine Complexes of Palladium, Crystal Structure, Catalysis, -Lactones Phosphinoalkylnitriles R2P-(CH2… (More)
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2007
2007
Photoelectro-synergistic catalysis combined with a FIA system application on determination of chemical oxygen demand.
In this paper, photoelectro-synergistic catalysis oxidation of organics in the water on Ti/TiO(2)/PbO(2) electrode was… (More)
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1998
1998
In vivo evidence of free radical formation after asbestos instillation: an ESR spin trapping investigation.
It has been postulated that the in vivo toxicity of asbestos results from its catalysis of free radical generation. We examined… (More)
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