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catalysis of free radical formation

Known as: catalysis of free radical generation, catalysis of free-radical biosynthesis, catalysis of free-radical generation 
Catalysis of a reaction that generates a free radical, a highly reactive molecule with an unsatisfied electron valence pair. [GOC:jl]
National Institutes of Health

Papers overview

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Highly Cited
2019
Highly Cited
2019
Asymmetric Induction and Enantiodivergence in Catalytic Radical C-H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution.
Control of enantioselectivity remains a major challenge in radical chemistry. The emergence of metalloradical catalysis (MRC… 
Highly Cited
2019
Highly Cited
2019
Plasmon-Driven Catalysis on Molecules and Nanomaterials.
As a new class of photocatalysts, plasmonic noble metal nanoparticles with the unique ability to harvest solar energy across the… 
Review
2019
Review
2019
Synthetic Photoelectrochemistry
Abstract Photoredox catalysis (PRC) and synthetic organic electrochemistry (SOE) are often considered competing technologies in… 
Highly Cited
2017
Highly Cited
2017
Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis.
Donor-substituted diazo reagents, generated in situ from sulfonyl hydrazones in the presence of base, can serve as suitable… 
2016
2016
Intramolecular 1,5-C(sp3)–H radical amination via Co(ii)-based metalloradical catalysis for five-membered cyclic sulfamides
Synthesis of strained five-membered cyclic sulfamides has been achieved for the first time by intramolecular 1,5-C(sp3)–H… 
2014
2014
Direct sp(3)C-H acroleination of N-aryl-tetrahydroisoquinolines by merging photoredox catalysis with nucleophilic catalysis.
Sequence catalysis merging photoredox catalysis (PC) and nucleophilic catalysis (NC) has been realized for the direct sp(3) C-H… 
2005
2005
Fluorocarbon soluble copper(II) carboxylate complexes with nonfluoroponytailed nitrogen ligands as precatalysts for the oxidation of alkenols and alcohols under fluorous biphasic or thermomorphic…
This fluorous biphasic catalysis (FBC) contribution was focused on the synthesis and characterization of new fluorous soluble R(f… 
2003
2003
Fluorous biphasic catalysis: synthesis and characterization of copper(I) and copper(II) fluoroponytailed 1,4,7-Rf-TACN and 2,2'-Rf-bipyridine complexes--their catalytic activity in the oxidation of…
In this contribution on fluorous biphasic catalysis (FBC), we present the synthesis and characterization of new copper complexes… 
1998
1998
In vivo evidence of free radical formation after asbestos instillation: an ESR spin trapping investigation.
Highly Cited
1998
Highly Cited
1998
The solvent-protected core of the hairpin ribozyme-substrate complex.
The complex between the hairpin ribozyme and its substrate consists of two domains that must interact in order to form a… 
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