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catalysis of free radical formation

Known as: catalysis of free radical generation, catalysis of free-radical biosynthesis, catalysis of free-radical generation 
Catalysis of a reaction that generates a free radical, a highly reactive molecule with an unsatisfied electron valence pair. [GOC:jl]
National Institutes of Health

Papers overview

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2019
2019
Plasmon-Driven Catalysis on Molecules and Nanomaterials.
As a new class of photocatalysts, plasmonic noble metal nanoparticles with the unique ability to harvest solar energy across the… Expand
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2019
2019
Asymmetric Induction and Enantiodivergence in Catalytic Radical C-H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution.
Control of enantioselectivity remains a major challenge in radical chemistry. The emergence of metalloradical catalysis (MRC… Expand
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2017
2017
Iminium Catalysis inside a Self-Assembled Supramolecular Capsule: Scope and Mechanistic Studies.
Although iminium catalysis has become an important tool in organic chemistry, its combination with supramolecular host systems… Expand
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2017
2017
Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis.
Donor-substituted diazo reagents, generated in situ from sulfonyl hydrazones in the presence of base, can serve as suitable… Expand
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2016
2016
Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides by Cobalt(II)-Based Metalloradical Catalysis: Effective Construction of Strained Heterobicyclic Structures.
Cobalt(II)-based metalloradical catalysis (MRC) has been successfully applied for effective construction of the highly strained 2… Expand
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2015
2015
Stereoselective radical C–H alkylation with acceptor/acceptor-substituted diazo reagents via Co(ii)-based metalloradical catalysis† †Electronic supplementary information (ESI) available. CCDC 1020629…
Co(II)-based metalloradical catalysis has been, for the first time, successfully applied for asymmetric intramolecular C-H… Expand
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2014
2014
Direct sp(3)C-H acroleination of N-aryl-tetrahydroisoquinolines by merging photoredox catalysis with nucleophilic catalysis.
Sequence catalysis merging photoredox catalysis (PC) and nucleophilic catalysis (NC) has been realized for the direct sp(3) C-H… Expand
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2005
2005
Fluorocarbon soluble copper(II) carboxylate complexes with nonfluoroponytailed nitrogen ligands as precatalysts for the oxidation of alkenols and alcohols under fluorous biphasic or thermomorphic…
This fluorous biphasic catalysis (FBC) contribution was focused on the synthesis and characterization of new fluorous soluble R(f… Expand
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1998
1998
The solvent-protected core of the hairpin ribozyme-substrate complex.
The complex between the hairpin ribozyme and its substrate consists of two domains that must interact in order to form a… Expand
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1998
1998
In vivo evidence of free radical formation after asbestos instillation: an ESR spin trapping investigation.
It has been postulated that the in vivo toxicity of asbestos results from its catalysis of free radical generation. We examined… Expand
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