callyspongiolide
National Institutes of Health
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A short enantioselective synthesis of the macrocyclic core 19 of callyspongiolide, involving a homocrotylboration of aldehyde 4…
The macrocyclic core of the cytotoxic marine natural product callyspongiolide (1) was forged by ring-closing alkyne metathesis…
The stereoselective total synthesis of cytotoxic marine macrolide callyspongiolide has been reported. The 14-membered…
A synthesis of the unsaturated side chain of callyspongiolide has been accomplished from two chiral building blocks prepared by…
Both epimers at C-21 in the proposed structure of (+)-callyspongiolide have been synthesized in a convergent and enantioselective…
We have elucidated the complete absolute configuration of callyspongiolide and unambiguously assigned its stereochemistry at the…