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bullvalene

 
National Institutes of Health

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2019
2019
Fluxional chemical species such as bullvalene have been a valuable source of inspiration and fundamental insight into the nature… Expand
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2018
2018
Herein we detail a practical synthesis of bullvalene and a variety of mono- and disubstituted analogues through cobalt-catalysed… Expand
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2016
2016
Abstract The gold(I)‐catalyzed oxidative cyclization of 7‐ethynyl‐1,3,5‐cycloheptatrienes gives 1‐substituted barbaralones in a… Expand
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2013
2013
Bullvalene is an organic molecule that spontaneously undergoes Cope rearrangements, resulting in a reconfiguration of its carbon… Expand
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2012
2012
The potential of an approach combining nuclear magnetic resonance (NMR) spectroscopy, molecular dynamics (MD) simulations, and… Expand
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2011
2011
Bullvalene is a structurally unique dynamic molecule thought to interconvert among 1.2 million degenerate isomers. The… Expand
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2009
2009
This Account highlights William von Eggers Doering's important discoveries in many fields of chemistry. His synthetic and… Expand
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2005
2005
[structure: see text] B3LYP/6-31G* calculations have been used to investigate the origins of the relative barrier heights for the… Expand
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2005
2005
Epoxidation of bullvalene (1) with a neutralized solution of Oxone gave racemic trisepoxide rac-6 in 93 % isolated yield. Its… Expand
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1986
1986
A low-temperature neutron diffraction refinement of the crystal structure of bullvalene, C/sub 10/H/sub 10/, tricyclo(3.3.2.0/sup… Expand
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