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bis(phenylsulfonyl)methane

National Institutes of Health

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3 relations

Broader (2)

MethaneSulfones
analogs & derivatives

Papers overview

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2018
2018
Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration.
An effective dehydrochlorination of bis(phenylsulfonyl)alkane to prepare alkene building blocks is developed. The elimination… 
2018
2018
Sulfones as Synthetic Linchpins: Transition-Metal-Free sp3 -sp2 and sp2 -sp2 Cross-Couplings Between Geminal Bis(sulfones) and Organolithium Compounds.
A valuable umpolung strategy that highlights the ambiphilic nature of the bis(phenylsulfonyl)methyl synthon and demonstrates its… 
2015
2015
Palladium-Catalyzed Triple Cyclization of 2,7-Alkadiynylic Carbonates with Allenes Bearing a Carbon Nucleophile.
Palladium-catalyzed tandem reactions of 2,7-alkadiynylic carbonates with allenes bearing a carbon nucleophile such as malonate… 
Review
2014
Review
2014
Base free catalyzed enantioselective Michael reaction of bis(phenylsulfonyl)methane to α,β -unsaturated aldehydes under iminium activation.
The Michael reaction of bis(phenylsulfonyl)methane with α,β-unsaturated aldehydes in the presence of catalytic amounts of a… 
2011
2011
Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates.
The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with bis(phenylsulfonyl)methane is… 
2011
2011
Catalytic asymmetric Michael reactions of α,β-unsaturated ketones with sulfonyl-containing nucleophiles: chiral synthesis of (R)-muscone and (S)-celery ketone.
Asymmetric Michael reaction between aliphatic (I) or alicyclic α,β-unsaturated ketones (VII) and sulfonyl-containing nucleophiles… 
2005
2005
Synthesis of mono- and geminal dimetalated carbanions of bis(phenylsulfonyl)methane using alkali metal bases and structural comparisons with lithiated bis(phenylsulfonyl)imides.
The alpha,alpha'-stabilized carbanion complexes [(PhSO2)2CHLi.THF]1, [(PhSO2)2CHNa.THF]2 and [(PhSO2)2CHK]3 were prepared by the… 
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