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bis(phenylsulfonyl)methane

National Institutes of Health

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3 relations

Broader (2)

MethaneSulfones
analogs & derivatives

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2018
2018
Sulfones as Synthetic Linchpins: Transition-Metal-Free sp3 -sp2 and sp2 -sp2 Cross-Couplings Between Geminal Bis(sulfones) and Organolithium Compounds.
A valuable umpolung strategy that highlights the ambiphilic nature of the bis(phenylsulfonyl)methyl synthon and demonstrates its… Expand
2018
2018
Bis(phenylsulfonyl)methane mediated synthesis of olefins via a halogen elimination and double bond migration.
An effective dehydrochlorination of bis(phenylsulfonyl)alkane to prepare alkene building blocks is developed. The elimination… Expand
2015
2015
Palladium-Catalyzed Triple Cyclization of 2,7-Alkadiynylic Carbonates with Allenes Bearing a Carbon Nucleophile.
Palladium-catalyzed tandem reactions of 2,7-alkadiynylic carbonates with allenes bearing a carbon nucleophile such as malonate… Expand
Review
2014
Review
2014
Base free catalyzed enantioselective Michael reaction of bis(phenylsulfonyl)methane to α,β -unsaturated aldehydes under iminium activation.
The Michael reaction of bis(phenylsulfonyl)methane with α,β-unsaturated aldehydes in the presence of catalytic amounts of a… Expand
2011
2011
Enantioselective organocatalytic asymmetric allylic alkylation. Bis(phenylsulfonyl)methane addition to MBH carbonates.
The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with bis(phenylsulfonyl)methane is… Expand
2011
2011
Catalytic asymmetric Michael reactions of α,β-unsaturated ketones with sulfonyl-containing nucleophiles: chiral synthesis of (R)-muscone and (S)-celery ketone.
The chemistry of the sulfonyl group has found numerous applications in organic and natural-product synthesis, with one of the… Expand
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2009
2009
Palladium-catalyzed regioselective cyclopropanating allenylation of (2,3-butadienyl)malonates with propargylic carbonates and their application to synthesize cyclopentenones.
An efficient and highly regioselective route to synthesize polysubstituted 1,3,4-alkatrien-2-yl cyclopropane derivatives via Pd(0… Expand
2005
2005
Synthesis of mono- and geminal dimetalated carbanions of bis(phenylsulfonyl)methane using alkali metal bases and structural comparisons with lithiated bis(phenylsulfonyl)imides.
The alpha,alpha'-stabilized carbanion complexes [(PhSO2)2CHLi.THF]1, [(PhSO2)2CHNa.THF]2 and [(PhSO2)2CHK]3 were prepared by the… Expand
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