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bis(iodozincio)methane

 
National Institutes of Health

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2 relations

Broader (1)

Methane
analogs & derivatives

Papers overview

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2017
2017
Preparation of Organozinc Reagents via Catalyst Controlled Three-Component Coupling between Alkyne, Iodoarene, and Bis(iodozincio)methane.
Three-component coupling between an alkyne, iodoarene, and bis(iodozincio)methane yields allylic zinc with a tetrasubstituted… Expand
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2015
2015
Preparation of cycloheptane ring by nucleophilic cyclopropanation of 1,2-diketones with bis(iodozincio)methane.
The nucleophilic cyclopropanation of hexa-1,5-diene-3,4-diones with bis(iodozincio)methane afforded the Zn alkoxides of cis… Expand
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2013
2013
Catalytic asymmetric aldol-type reaction of zinc enolate equivalent of amides.
Treatment of phenyl isocyanate with bis(iodozincio)methane gave a zinciomethylenated product, which acts as an amide-enoate… Expand
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2010
2010
A tandem reaction initiated by 1,4-addition of bis(iodozincio)methane for 1,3-diketone formation.
Treatment of an gamma-acyloxy-alpha,beta-unsaturated ketone with bis(iodozincio)methane leads to a novel tandem reaction… Expand
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2010
2010
Stereospecific construction of chiral tertiary and quaternary carbon by nucleophilic cyclopropanation with bis(iodozincio)methane.
The reaction of a ketone having a leaving group at the alpha-position, such as alpha,beta-epoxy ketone or alpha-sulfonyloxy… Expand
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2010
2010
Reaction pathway of methylenation of carbonyl compounds with bis(iodozincio)methane.
About 40 years have passed since methylene dizinc reagent was discovered as a substitute for Wittig reagent. Density functional… Expand
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2010
2010
1,4-Addition of bis(iodozincio)methane to α,β-unsaturated ketones: chemical and theoretical/computational studies.
1,4-Addition of bis(iodozincio)methane to simple α,β-unsaturated ketones does not proceed well; the reaction is slightly… Expand
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2009
2009
Nucleophilic cyclopropanation reaction with bis(iodozincio)methane by 1,4-addition to alpha,beta-unsaturated carbonyl compounds.
Treatment of alpha,beta-unsaturated ketones with an electrophilic site at the gamma-position in the presence of trimethylsilyl… Expand
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2006
2006
Transition-metal-catalyzed sequential cross-coupling of bis(iodozincio)methane and -ethane with two different organic halides.
Bis(iodozincio)methane, prepared from diiodomethane and zinc, reacts with an organic halide in the presence of a transition-metal… Expand
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2005
2005
Preparation and reaction of 2-aryl-3-silyl-1,3-butadiene.
[reaction: see text] A conjugated pi-electron compound, 2-aryl-3-silyl-1,3-butadiene, was easily prepared from 1-benzyloxy-3… Expand
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