aza-pinacol
National Institutes of Health
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A visible-light-mediated photocatalytic umpolung synthesis of 1,3-diamines from in situ-generated imines and dehydroalanine…
Arylboronic acids or arylboronates have found widespread applications in transition-metal-catalyzed C C bond forming reactions…
Stereocontrolled access to the hexacyclic core of FD-594 has been achieved. The key steps include the intramolecular S(N)Ar…
Reaction of (diisopropylamino)chloroboryl ethers of alkynols with alkynylstannanes in the presence of nickel catalysts afforded…
Functionalized vinyl pinacol boronates suitable for Suzuki cross-coupling reactions are synthesized using ruthenium-catalyzed…
Under palladium catalysis, o-bromobenzeneboronic acid can be coupled with 1-bromonaphthalene (6) and with oligocyclic bromoarenes…
[reaction: see text] Aryl chlorides bearing electron-withdrawing groups react with bis(pinacol)borane 1 to give aryl boronates in…
A new route to 24-nortriterpene derivatives with 2-hydroxy-Delta(1,4)-cyclohexadien-3-one A-rings from triterpene precursors has…
To investigate the effects of electron-donating and electron-withdrawing substituents upon the reaction of porphyrins with osmium…
Aliphatic aldehydes as well as aromatic aldehydes can be converted by means of cerium-catalyzed pinacol coupling [Eq. (1)]. The…